Chemoselective Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of (Diborylmethyl)silanes with Alkenyl Bromides
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SCOPUS
- Title
- Chemoselective Palladium-Catalyzed Suzuki-Miyaura Cross-Coupling of (Diborylmethyl)silanes with Alkenyl Bromides
- Authors
- KIM, JUNGHOON; LEE, EUNSUNG; CHO, SEUNG HWAN
- Date Issued
- 2019-07
- Publisher
- WILEY-V C H VERLAG GMBH
- Abstract
- Herein, we report the development of a palladium-catalyzed chemoselective cross-coupling of (diborylmethyl)silanes with alkenyl bromides. The reaction shows broad scope with respect to alkenyl bromides and (diborylmethyl)silanes, affording a range of alpha-silyl-substituted allylic boronate esters in good-to-excellent yields. The practicality of the developed coupling reaction is demonstrated by the gram-scale synthesis of alpha-silyl-substituted allylic boronate ester.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/99919
- DOI
- 10.1002/ajoc.201900328
- ISSN
- 2193-5807
- Article Type
- Article
- Citation
- ASIAN JOURNAL OF ORGANIC CHEMISTRY, vol. 8, no. 9, page. 1664 - 1667, 2019-07
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