X-ray Direct Observation of Reactions and Labile Species on the Basis of Crystal Design
SCIE
SCOPUS
- Title
- X-ray Direct Observation of Reactions and Labile Species on the Basis of Crystal Design
- Authors
- Kawano, M
- Date Issued
- 2014-05-15
- Publisher
- CHEMICAL SOC JAPAN
- Abstract
- This account reviews recent development of in situ crystallographic study of reactive intermediates using the cryo-trapping method. Starting from the basic concept of a reaction cavity in a crystal, we succeeded in not only observing photoinduced reactive species such as radical, carbene, and nitrene but also establishing a unique approach, crystalline molecular flask, to observe labile species in chemical reactions in a crystal. On the basis of such a crystalline reaction field design, we successfully observed irreversible reactive intermediates in a crystal.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/9864
- DOI
- 10.1246/BCSJ.20130217
- ISSN
- 0009-2673
- Article Type
- Article
- Citation
- BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, vol. 87, no. 5, page. 577 - 592, 2014-05-15
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