Solvent-Dependent Molecular Structure of Ionic Species Directly Measured by Ultrafast X-Ray Solution Scattering
SCIE
SCOPUS
- Title
- Solvent-Dependent Molecular Structure of Ionic Species Directly Measured by Ultrafast X-Ray Solution Scattering
- Authors
- KIM, KYUNG HWAN; Jae Hyuk Lee; Joonghan Kim; Shunsuke Nozawa; Tokushi Sato; Ayana Tomita; Kouhei Ichiyanagi; Hosung Ki; Jeongho Kim; Shin-ichi Adachi; Hyotcherl Ihee
- Date Issued
- 2013-04-18
- Publisher
- AMER PHYSICAL SOC
- Abstract
- Ionic species often play important roles in chemical reactions occurring in water and other solvents, but it has been elusive to determine the solvent-dependent molecular structure with atomic resolution. The triiodide ion has a molecular structure that sensitively changes depending on the type of solvent and its symmetry can be broken by strong solute-solvent interaction. Here, by applying pump-probe x-ray solution scattering, we characterize the exact molecular structure of I-3(-) ion in water, methanol, and acetonitrile with subangstrom accuracy. The data reveal that I-3(-) ion has an asymmetric and bent structure in water. In contrast, the ion keeps its symmetry in acetonitrile, while the symmetry breaking occurs to a lesser extent in methanol than in water. The symmetry breaking of I-3(-) ion is reproduced by density functional theory calculations using 34 explicit water molecules, confirming that the origin of the symmetry breaking is the hydrogen-bonding interaction between the solute and solvent molecules. DOI: 10.1103/PhysRevLett.110.165505
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/94149
- DOI
- 10.1103/PhysRevLett.110.165505
- ISSN
- 0031-9007
- Article Type
- Article
- Citation
- PHYSICAL REVIEW LETTERS, vol. 110, no. 16, 2013-04-18
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