Ruthenium Bisammine Complex and Its Reaction with Aryl Azides
SCIE
SCOPUS
- Title
- Ruthenium Bisammine Complex and Its Reaction with Aryl Azides
- Authors
- Park, Jin Yong; Kim, Yongjin; Bae, Dae Young; Rhee, Young Ho; Park, Jaiwook
- Date Issued
- 2017-09
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A ruthenium bisammine complex was formed in the reaction of ruthenium 1,4-dibenzyltetraazadiene complex with primary amines at room temperature, which was a versatile precursor for the synthesis of various Ru(II) complexes through ligand exchange reactions. In the reaction with azidobenzene, ruthenium 1,4-diphenyltetraaza-1,3-diene complex was formed, while ruthenium imido complexes were given in the reaction with bulky aryl azides such as 2-azido-1,3-dimethylbenzene and 2-azido-1,3-diisopropylbenzene. The ruthenium imido complexes showed high catalytic activity in the reaction of alkyl azides with primary amines to afford N-substituted imines.
- Keywords
- DEMANDING CYCLOPENTADIENYL LIGANDS; HALF-SANDWICH COMPLEXES; N-UNSUBSTITUTED IMINES; IMIDO COMPLEXES; ALKYL AZIDES; CRYSTAL-STRUCTURE; BENZYL AZIDES; CYCLOADDITION; ZIRCONIUM; AMINES
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/50608
- DOI
- 10.1021/acs.organomet.7b00403
- ISSN
- 0276-7333
- Article Type
- Article
- Citation
- ORGANOMETALLICS, vol. 36, no. 18, page. 3471 - 3476, 2017-09
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