Intrinsic Viscosity of Cyclic Polystyrene
SCIE
SCOPUS
- Title
- Intrinsic Viscosity of Cyclic Polystyrene
- Authors
- Jeong, Youncheol; Jin, Ye; Chang, Taihyun; Uhlik, Filip; Roovers, Jacques
- Date Issued
- 2017-10
- Publisher
- AMER CHEMICAL SOC
- Abstract
- The intrinsic viscosity of cyclic polystyrenes (C-PS) and linear polystyrenes (L-PS) with molecular weight (MW) ranging from 16K to 370K was measured in THF using size exclusion chromatography coupled with a triple detection system. The C-PS samples were prepared by a ring-closure reaction of telechelic linear precursor synthesized by anionic polymerization. As-synthesized C-PS samples after the ring closure reaction contain various byproducts, and they were fractionated by liquid chromatography at the critical condition to obtain highly pure C-PS. While the intrinsic viscosity of L-PS agrees well with the literature data, C-PS shows significantly lower value than the literature values. The Mark-Houwink exponent of C-PS is 0.67, somewhat lower than 0.70 for L-PS in the good solvent over the MW range examined. Therefore, the ratio of the intrinsic viscosity of C-PS to L-PS (g' = [eta](C)/[eta](L)) in THF is not MW independent but decreases as MW increases (0.63 >= [eta](C)/[eta](L) >= 0.57). The trend of intrinsic viscosity agrees well with the computer simulation result. The discrepancy in [eta](C) from the literature values can largely be attributed to the contamination of linear byproducts in the earlier studies.
- Keywords
- EXPANSION METATHESIS POLYMERIZATION; CHROMATOGRAPHIC CRITICAL CONDITION; RING-SHAPED POLYSTYRENES; DILUTE-SOLUTION; HYDRODYNAMIC PROPERTIES; MONTE-CARLO; POLYMERS; MACROMOLECULES; CHAINS; RENORMALIZATION
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/50563
- DOI
- 10.1021/acs.macromol.7b01511
- ISSN
- 0024-9297
- Article Type
- Article
- Citation
- MACROMOLECULES, vol. 50, no. 19, page. 7770 - 7776, 2017-10
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