New dithienophosphole-based donor–acceptor alternating copolymers: Synthesis and structure property relationships in OFET
SCIE
SCOPUS
- Title
- New dithienophosphole-based donor–acceptor alternating copolymers: Synthesis and structure property relationships in OFET
- Authors
- Sung, Min Jae; Kim, Yebyeol; Lee, Sang Bong; Lee, Gi Back; An, Tae Kyu; Cha, Hyojung; Kim, Se Hyun; Park, Chan Eon; Kim, Yun-Hi
- Date Issued
- 2016-02
- Publisher
- Elsevier
- Abstract
- Two donor acceptor conjugated copolymers comprised of a novel dithienophosphole (DTP) as the acceptor unit and bithiophene (BT) or decylthiophenebenzodithiophene (DTBDT) as the donor unit were synthesized and characterized to elucidate the relationship between donor acceptor (D-A) architecture and organic field-effect transistors (OFETs) performance. These characteristics of D-A copolymers were affected by the structural suitability of donor and acceptor units. Poly(DTP-BT) had an ordered structure that facilitated charge carrier transfer. The crystallinity of poly(DTP-BT) increased as annealing temperature (T-ann) increased. In contrast, poly(DTP-DTBDT) was amorphous regardless of Tann due to the long alkyl chains of the DTBDT units. OFET devices made with poly(DTP-BT) and annealed at 200 degrees C exhibit a highly crystalline morphology and a relatively high field-effect mobility (4.9 x 10(-3) cm(2)/(V.s)).
- Keywords
- Organic field effect transistor (OFET); Dithienophosphole; Donor-acceptor (D-A) architecture; X-ray diffraction; Polymeric semiconductor; Well ordered crystalline structure
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/50129
- DOI
- 10.1016/j.dyepig.2015.09.026
- ISSN
- 1566-1199
- Article Type
- Article
- Citation
- Dyes and Pigments, vol. 125, page. 316 - 322, 2016-02
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