A Layer-Structured Electrode Material Reformed by a PO4-O2 Hybrid Framework toward Enhanced Lithium Storage and Stability
SCIE
SCOPUS
- Title
- A Layer-Structured Electrode Material Reformed by a PO4-O2 Hybrid Framework toward Enhanced Lithium Storage and Stability
- Authors
- S. H. Min; M. R. Jo; Y. -I Kim; Y. -M. Kang; CHOI, SI YOUNG
- Date Issued
- 2016-04-06
- Publisher
- WILEY-V C H VERLAG GMBH
- Abstract
- The surface framework of LiCoO2 is modified through a surface treatment called phosphidation, which suppressed the unwanted phase transition occurring above 4.2 V. The surface instability of LiCoO2 toward organic electrolytes is simultaneously improved by changing its surface structure from an O-2-based framework to a PO4-based framework that can protect against HF attack during cycling. Phosphidated LiCoO2 is successfully synthesized that showed greater stability in its bulk and surface structures. The phosphidated form enables faster Li+ diffusion and prevents irreversible phase transitions, especially when charged above 4.2 V, and consequently demonstrates excellent cycling performance and rate capabilities. The improved kinetics and stability resulting from phosphidation make LiCoO2 highly suitable as a high-voltage cathode material for use in lithium ion batteries.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/39294
- DOI
- 10.1002/aenm.201501717
- ISSN
- 1614-6832
- Article Type
- Article
- Citation
- Advanced Energy Materials, vol. 6, no. 7, 2016-04-06
- Files in This Item:
- There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.