Activation of C–F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexe
SCIE
SCOPUS
- Title
- Activation of C–F bonds in fluoroarenes by N-heterocyclic carbenes as an effective route to synthesize abnormal NHC complexe
- Authors
- Kim, Youngsuk; Lee, Eunsung
- Date Issued
- 2016-08
- Publisher
- Royal Society of Chemistry
- Abstract
- IPr (1a) reacts with octafluorotoluene by an unexpected sequential substitution of fluorides in two separate rings. The resulting tetra-substituted imidazolium salt was isolated and elaborated into Ag(I) and Au(I) complexes with a novel abnormal NHC ligand. Both IPr (1a) and IMes (1b) were also found to be moderately reactive by nucleophilic substitution of the aromatic C-F bond in a weakly-activated fluoro-arene, 1-fluoro-4-trifluoromethylbenzene (5).
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/37964
- DOI
- 10.1039/C6CC04896J
- ISSN
- 1359-7345
- Article Type
- Article
- Citation
- CHEMICAL COMMUNICATIONS, vol. 52, no. 72, page. 10922 - 10925, 2016-08
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- There are no files associated with this item.
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