>10% Efficiency Polymer:Fullerene Solar Cells with Polyacetylene-Based Polyelectrolyte Interlayers
SCIE
SCOPUS
- Title
- >10% Efficiency Polymer:Fullerene Solar Cells with Polyacetylene-Based Polyelectrolyte Interlayers
- Authors
- Nam, S; Seo, J; Han, H; Kim, H; Hahm, S.G; Ree, M; Gal, Y.-S; Anthopoulos, T.D; Bradley, D.D.C; Kim, Y.
- Date Issued
- 2016-12-07
- Publisher
- Wiley
- Abstract
- Polymer solar cells have gained great attention due to their tremendous potential for applications in light-weight, large-area, and flexible photovoltaic modules fabricated via continuous roll-to-roll processes. Despite the significant progress, however, their efficiency and operating stability are still inadequate for commercial applications. Interfacial engineering of the electron-collecting buffer layer and the organic photoactive layer through the use of organic dipole interlayers, has been proposed as a simple and scalable way to improve the overall solar cell performance. Here, highly efficient inverted polymer: fullerene solar cells have been successfully developed with a power conversion efficiency of over 10%. The bulk heterojunction layer consists of the poly[4,8-bis(5-(2-ethylhexyl) thiophen-2-yl) benzo[1,2-b: 4,5-b] dithiophene-alt-3-fluorothieno[3,4-b] thiophene-2-carboxylate] (PTB7-Th) and the [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM), as the electron donor and electron acceptor, respectively. Key to this success is the insertion of the ionic polyacetylene-based conjugated polymer, poly(N-dodecyl-2-ethynylpyridinium bromide), as an interfacial dipole layer. The latter is shown to lower the work function of the electron transporting zinc oxide layer and increase the built-in potential, consequently facilitating efficient charge transport/extraction. Optimized solar cells exhibit power conversion efficiency values exceeding 10% while their operating stability under continuous solar-simulated illumination is significantly enhanced when ultraviolet light is effectively blocked using a suitable optical filter.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/37942
- DOI
- 10.1002/ADMI.201600415
- ISSN
- 2196-7350
- Article Type
- Article
- Citation
- Advanced Materials Interfaces, vol. 3, no. 23, page. 1600415 - 1600422, 2016-12-07
- Files in This Item:
- There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.