A nearly quantitative synthetic approach towards monocyclic polystyrenes and the solvent, concentration and molecular weight effect on cyclic yield
SCIE
SCOPUS
- Title
- A nearly quantitative synthetic approach towards monocyclic polystyrenes and the solvent, concentration and molecular weight effect on cyclic yield
- Authors
- Gao, LF; Oh, J; Chang, T; Chen, DX; Li, XH; Yang, XM; Tu, YF; Zhu, XL; Li, CY
- Date Issued
- 2016-09-28
- Publisher
- ELSEVIER SCI LTD
- Abstract
- We report herein the effects of solvent, concentration, and molecular weight of alpha-alkynyl-omega-azido polystyrenes (l-PS-N-3) on the synthesis of monocyclic polystyrenes (c-PS) by intra-chain coupling l-PS-N-3 via Cu-catalyzed azide/alkyne cycloaddition method. By using fully end-functionalized l-PS-N-3 as precursors, the optimum cyclization conditions to synthesize high purity c-PS (>99% by SEC) are revealed, at concentrations around 7.9 mu mol/L in DMF. The c-PS products are fully characterized by SEC, LCCC, H-1 NMR, and MALDI-TOF Mass spectrometry. The yield of c-PS decreases with increment of concentration of l-PS-N-3 as predicted by Jacobson and Stockmayer's equation. Interestingly, among the three studied PS samples with different molecular weight (similar to 4k, 9k, 14k Da), the medium one (PS9k) provides the best c-PS yield, while in the three studied solvent (toluene, DMF, cyclohexane), DMF gives the best yied. The results reveal that the PS chain conformation in the solution, which is affected by the solvent and molecular weights, plays an important role in the intra-chain cyclization reaction. (C) 2016 Elsevier Ltd. All rights reserved.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/36786
- DOI
- 10.1016/j.polymer.2016.08.086
- ISSN
- 0032-3861
- Article Type
- Article
- Citation
- POLYMER, vol. 101, page. 379 - 387, 2016-09-28
- Files in This Item:
- There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.