Two-dimensional assembly of rod amphiphiles into planar networks
SCIE
SCOPUS
- Title
- Two-dimensional assembly of rod amphiphiles into planar networks
- Authors
- Kim, JK; Lee, E; Jeong, YH; Lee, JK; Zin, WC; Lee, M
- Date Issued
- 2007-05-16
- Publisher
- AMER CHEMICAL SOC
- Abstract
- We present here the spontaneous formation of nanoporous sheets in aqueous solution without a template to guide them, which is based on the self-assembly of dumbbell-shaped rod amphiphiles driven by a fine balance of anisotropic hydrophobic interactions, and steric constraints endowed with bulky dendritic wedges. These planar nets transform into closed 2D sheets when the rod segment increases in length. Such a unique arrangement of rigid rod building blocks might provide a new strategy for the design of nanoporous materials simultaneously with biological and electro-optical functions.
- Keywords
- DIBLOCK COPOLYMERS; MICELLES; SHEETS
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/29444
- DOI
- 10.1021/JA071394Y
- ISSN
- 0002-7863
- Article Type
- Article
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 129, no. 19, page. 6082 - +, 2007-05-16
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