Host-Guest Interactions in Zeolites P1, SUZ-4 and ZSM-57 Containing N,N,N,N´,N´,N´-Hexaethylpentane-diammonium Ion as a Guest Molecule
SCIE
- Title
- Host-Guest Interactions in Zeolites P1, SUZ-4 and ZSM-57 Containing N,N,N,N´,N´,N´-Hexaethylpentane-diammonium Ion as a Guest Molecule
- Authors
- Paik, WC; Shin, CH; Lee, JM; Ahn, BJ; Hong, SB
- Date Issued
- 2001-10-18
- Publisher
- American Chemical Society
- Abstract
- The H-1-C-13 CP MAS NMR and Raman spectra of N,N,N,N',N',N'-hexaethylpentanediammonium (Et-6-diquat-5) ions encapsulated within P1, SUZ-4, and ZSM-57 zeolites are presented. The Et-6-diquat-5 molecules occluded are found to adopt distinct molecular conformations in order to fit in the pores of each zeolite host. Computer modeling studies show that encapsulation of Et-6-diquat-5 in the small-pore zeolite P1 is not energetically favorable. However, a remarkable match between the conformation of guest molecule and the geometry of the host structure is observed for the medium-pore zeolites SUZ-4 and ZSM-57, revealing the existence of organic structure-directing effect. The overall results of this study suggest that conformations available to the flexible, linear organic cation like Et-6-diquat-5 may differ considerably according to the type and concentration of alkali cations present in the zeolite synthesis mixture, which is a critical factor affecting the phase selectivity of the crystallization. It thus appears that the modification of conformations of flexible organic structure-directing agents by varying the type and concentration of alkali cations may be an area of considerable possibility for finding new zeolite structures.
- Keywords
- TETRAMETHYLAMMONIUM ION; SKELETAL ISOMERIZATION; CATALYTIC EVALUATION; FRAMEWORK TOPOLOGY; ORGANIC-MOLECULES; RAMAN-SPECTRA; POSITION; TEMPLATE; CATIONS
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/27723
- DOI
- 10.1021/jp0101413
- ISSN
- 1089-5647
- Article Type
- Article
- Citation
- JOURNAL OF PHYSICAL CHEMISTRY, vol. 105, no. 41, page. 9994 - 10000, 2001-10-18
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