Enhanced Magnetization and Modulated Orbital Hybridization in Epitaxially Constrained BiFeO3 Thin Films with Rhombohedral Symmetry
SCIE
SCOPUS
- Title
- Enhanced Magnetization and Modulated Orbital Hybridization in Epitaxially Constrained BiFeO3 Thin Films with Rhombohedral Symmetry
- Authors
- Ryu, S; Kim, JY; Shin, YH; Park, BG; Son, JY; Jang, HM
- Date Issued
- 2009-11-10
- Publisher
- AMER CHEMICAL SOC
- Abstract
- BiFeO3 (BFO) is currently considered to be the most promising candidate material for device applications of room-temperature multiferroics. However, there exist some controversial arguments oil the origin of the enhanced magnetization and polarization observed in the epitaxially constrained BFO thin film heterostructures. More specifically, the issue can be addressed by the following question: Can the epitaxial strain enhance the magnetization and the ferroelectric polarization in BFO? To clarify this controversial issue, we have systematically examined the magnetization characteristics of the rhombohedral BFO Films epitaxially grown on (1 1 1)-oriented SrTiO3 (STO) in terms of the in-plane misfit strain between the BFO layer and the STO substrate. The increase in the saturation magnetization with decreasing film thickness was found to be closely related with the misfit strain. By carefully examining synchrotron X-ray absorption spectra, we have further correlated the enhanced magnetization in a highly strained film Willi the reduced degree of hybridization between Fe 3d and O 2p orbitals and with the splitting of the triplet t(2g) orbital into a(1g) and c(g)(pi) orbitals arising from the trigonal D-3d distortion.
- Keywords
- ELECTRONIC-STRUCTURE; ROOM-TEMPERATURE; POLARIZATION; HETEROSTRUCTURES; FERROELECTRICITY; NANOPARTICLES; LUFE2O4; SYSTEM; FIELD
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/26597
- DOI
- 10.1021/CM9014496
- ISSN
- 0897-4756
- Article Type
- Article
- Citation
- CHEMISTRY OF MATERIALS, vol. 21, no. 21, page. 5050 - 5057, 2009-11-10
- Files in This Item:
- There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.