Formation of an Iodide-Bridged Diruthenium Complex from [(n(5)- Ph4C4COH)(CO)(2)RuI] and [(Ph4C4CO)(CO)(2)Ru](2): An Efficient Catalyst for Alcohol Oxidation with Ag2O
SCIE
SCOPUS
- Title
- Formation of an Iodide-Bridged Diruthenium Complex from [(n(5)- Ph4C4COH)(CO)(2)RuI] and [(Ph4C4CO)(CO)(2)Ru](2): An Efficient Catalyst for Alcohol Oxidation with Ag2O
- Authors
- Do, Y; Ko, SB; Hwang, IC; Lee, KE; Lee, SW; Park, J
- Date Issued
- 2009-08-10
- Publisher
- AMER CHEMICAL SOC
- Abstract
- Iodide-bridged diruthenium complexes [(n(5) -2.5-R-2-3.4-Ph2C4COH) (CO)(2) Ru-(mu-I)-Ru(CO)(2)(n(4)-2.5-R-2-3.4-Ph2C4CO)] (6a, R=ph; 6b, R=Me) were formed from the reaction of (n(5-)2.5-3.4-Ph2C4COH)(CO)(2) RuI (2c, R=Ph;2d, R=Me) with [(2.5-R(2-)3.4-Ph2C4CO)(CO)(2)Ru](2) (7a, R=Ph; 7b, R=Me). The complexes exhibited a high catalytic activity for the oxidation of alcohols with silver oxide at room temperature.
- Keywords
- HYDROXYCYCLOPENTADIENYL RUTHENIUM HYDRIDE; DYNAMIC KINETIC RESOLUTION; SECONDARY ALCOHOLS; AEROBIC OXIDATION; HYDROGEN-TRANSFER; REDUCTION; ALDEHYDES; DEHYDROGENATION; MECHANISM; KETONES
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/26442
- DOI
- 10.1021/OM9003434
- ISSN
- 0276-7333
- Article Type
- Article
- Citation
- ORGANOMETALLICS, vol. 28, no. 15, page. 4624 - 4627, 2009-08-10
- Files in This Item:
- There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.