Direct observation of the labile imine formation through single-crystal-to-single-crystal reactions in the pores of a porous coordination network
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SCOPUS
- Title
- Direct observation of the labile imine formation through single-crystal-to-single-crystal reactions in the pores of a porous coordination network
- Authors
- Tsuyoshi Haneda; Kawano, M; Takehide Kawamichi; Makoto Fujita
- Date Issued
- 2008-02-06
- Publisher
- AMER CHEMICAL SOC
- Abstract
- We report an approach to in situ observation of unstable species produced by a single-cystal-to single-crystal chemical reaction. We succeeded in uniform formation and the direct observation of unstable imines in pores of a 3-D porous coordination network with aldehydes provided by guest exchange. Moreover, we found the remarkable dynamic motion of a part of the host framework by changing aldehydes.
- Keywords
- CATALYSIS; POLYMERS; MOLECULES; DESIGN
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/25762
- DOI
- 10.1021/ja7111564
- ISSN
- 0002-7863
- Article Type
- Article
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 130, no. 5, page. 1578 - +, 2008-02-06
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