Fabrication of a Vertically Aligned Ferroelectric Perovskite Nanowire Array on Conducting Substrate
SCIE
SCOPUS
- Title
- Fabrication of a Vertically Aligned Ferroelectric Perovskite Nanowire Array on Conducting Substrate
- Authors
- Im, B; Jun, H; Lee, KH; Lee, SH; Yang, IK; Jeong, YH; Lee, JS
- Date Issued
- 2010-08-24
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A new fabrication process of a vertically aligned ferroelectric perovskite PbTiO3 nanowire array on Ti substrate is presented. Polycrystalline TiO2 nanotubes are first fabricated by anodic oxidation of Ti foil and then treated hydrothermally in a lead acetate solution to obtain single-crystalline nanowires. This nanotube-to-nanowire transformation on conducting substrate could be described by a swelling-and-rupture mechanism, in which individually well-developed nanotubes are swollen and broken along the friction planes because of difference in the directions of expansion force. Nanowires with a uniform diameter of ca. 40 nm and a length of 10 mu m show single-crystalline nature over the entire length of nanowires and ultrahigh density corresponding to ca. 0.22 Tb inch(-2). The ferroelectric property of individual PbTiO3 nanowires and whole area of nanowire arrays has been demonstrated by piezo-response force microscopy.
- Keywords
- X-RAY-DIFFRACTION; THIN-FILMS; HYDROTHERMAL SYNTHESIS; TEMPLATE SYNTHESIS; NANOTUBE ARRAYS; BARIUM-TITANATE; LEAD TITANATE; PBTIO3; SPECTROSCOPY; 200-DEGREES-C
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/25378
- DOI
- 10.1021/CM101412D
- ISSN
- 0897-4756
- Article Type
- Article
- Citation
- CHEMISTRY OF MATERIALS, vol. 22, no. 16, page. 4806 - 4813, 2010-08-24
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