A FACILE METHOD FOR 2-THIOPHENACYLIDENETHIAZOLINE DERIVATIVES
SCIE
SCOPUS
- Title
- A FACILE METHOD FOR 2-THIOPHENACYLIDENETHIAZOLINE DERIVATIVES
- Authors
- KIM, J; KIM, JH; KIM, K; KIM, SH
- Date Issued
- 1993-07
- Publisher
- BLACKWELL PUBLISHING LTD
- Abstract
- The reactions of 2-alkyl-5-phenylisothiazole-3-thiones with 2-chloro-1,3-dicarbonyl compounds in chloroform gave the corresponding isothiazolium chlorides which, upon treatment at room temperature with sodium borohydride in a mixture of chloroform and ethanol, underwent S-N bond cleavage to give 3-alkyl-4,5-disubstituted-2-thiophenacylidenethiazolines. Similarly, treatment of the isothiazolium chlorides with triphenylphosphite in chloroform at 60-degrees afforded the same thiazoline derivatives.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/22036
- DOI
- 10.1002/jhet.5570300415
- ISSN
- 0022-152X
- Article Type
- Article
- Citation
- JOURNAL OF HETEROCYCLIC CHEMISTRY, vol. 30, no. 4, page. 929 - 938, 1993-07
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