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CRYSTAL-STRUCTURES OF (PLUS-OR-MINUS)-1,2/4,5-DI-O-ISOPROPYLIDENE-MYO-INOSITOL AND (PLUS-OR-MINUS)-1,2/5,6-DI-O-ISOPROPYLIDENE-MYO-INOSITOL - A CONFORMATIONAL-ANALYSIS

Title
CRYSTAL-STRUCTURES OF (PLUS-OR-MINUS)-1,2/4,5-DI-O-ISOPROPYLIDENE-MYO-INOSITOL AND (PLUS-OR-MINUS)-1,2/5,6-DI-O-ISOPROPYLIDENE-MYO-INOSITOL - A CONFORMATIONAL-ANALYSIS
Authors
CHUNG, SKKIM, KMCHANG, YOUNG TAERYU, YHWHANG, DM
Date Issued
1994-02
Publisher
ELSEVIER SCIENCE BV
Abstract
(+/-)-1,2:4,5-Di-O-isopropylidene-myo-inositol (1), C12H20O6, crystallises in the monoclinic space group, C2/c with unit-cell dimensions a = 22.587(3), b = 5.4204(3), and c = 22.174(4) Angstrom. (+/-)-1,2:5,6-di-O-isopropylidene-myo-inositol (2), C12H20O6, crystallises in the monoclinic space group, P2(1)/n with a = 11.543(3), b = 6.860(1), and c = 16.895(4) Angstrom. The inositol ring of 1 and 2 has a chair and skew conformation, respectively. Based on the crystalline conformations of 1 and 2, steric and hydrogen bonding features of the hydroxyl groups are discussed.
URI
https://oasis.postech.ac.kr/handle/2014.oak/21988
ISSN
0008-6215
Article Type
Article
Citation
CARBOHYDRATE RESEARCH, vol. 253, page. 13 - 18, 1994-02
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김기문KIM, KIMOON
Dept of Chemistry
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