Efficient catalytic racemization of secondary alcohols.
SCIE
SCOPUS
- Title
- Efficient catalytic racemization of secondary alcohols.
- Authors
- Koh, JH; Jeong, HM; Park, J
- Date Issued
- 1998-07-30
- Publisher
- PERGAMON-ELSEVIER SCIENCE LTD
- Abstract
- (eta(5)-Indenyl)RuCl(PPh3)(2) was found to efficiently catalyze the racemization of chiral alcohols such as (S)-1-phenylethan-1 -ol, (S)-1-phenylpropan-2-ol and (S)-4-phenylbutan-2-ol at room temperature in the presence of base. The catalytic activity of five other Ru(II) complexes was also investigated. The effects of varying reaction conditions such as reaction temperature, solvent, and base were investigated as well. (C) 1998 Elsevier Science Ltd. All rights reserved.
- Keywords
- racemization; alcohol; ruthenium; catalyst; INDENYL COMPLEXES; CYCLOPENTADIENYL; RUTHENIUM(II); KETONES
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/20717
- DOI
- 10.1016/S0040-4039(98)01116-2
- ISSN
- 0040-4039
- Article Type
- Article
- Citation
- TETRAHEDRON LETTERS, vol. 39, no. 31, page. 5545 - 5548, 1998-07-30
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- There are no files associated with this item.
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