ELECTRONIC EXCITATIONS ON THE ALKALI-METAL (NA,CS)-ADSORBED SI(111)7X7 SURFACES
SCIE
SCOPUS
- Title
- ELECTRONIC EXCITATIONS ON THE ALKALI-METAL (NA,CS)-ADSORBED SI(111)7X7 SURFACES
- Authors
- Lee, KD; Ahn, JR; Chung, JW
- Date Issued
- 1999-01
- Publisher
- SPRINGER VERLAG
- Abstract
- Electronic excitation spectra of the alkali-metal (AM) (Na,Cs)-adsorbed Si(111)7 x 7 surfaces have been investigated by using high-resolution electron energy loss spectroscopy. We find that AM induces metal-semiconductor transitions at the early stage of adsorption by completely filling half-filled Si adatom dangling-bend states. A loss peak of energy less than 0.31 eV appears as a precursor of the semi conducting phases, which disappears with increasing coverage, resulting in the formation of energy gaps of 0.43 eV and 1.08 eV for Cs and Na, respectively. Both Cs- and Na-adsorbed surfaces become metallic at saturation, in sharp contrast with the semiconducting K-saturated surface. We discuss the physical origin of the AM-induced loss peaks and its implications for the electrical phase transitions.
- Keywords
- SI(001) SURFACE; ADSORPTION; METALLIZATION; PHOTOEMISSION; SPECTROSCOPY; STATES; CS
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/20547
- DOI
- 10.1007/s003390050864
- ISSN
- 0947-8396
- Article Type
- Article
- Citation
- APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, vol. 68, no. 1, page. 115 - 118, 1999-01
- Files in This Item:
- There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.