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Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts SCIE SCOPUS
- Title
- Dynamic kinetic resolution of allylic alcohols mediated by ruthenium- and lipase-based catalysts
- Date Issued
- 2000-07-27
- Publisher
- AMER CHEMICAL SOC
- Abstract
- [GRAPHICS] An enzyme-metal combo reaction has been developed for the dynamic kinetic resolution of allylic alcohols in which racemic substrates are transformed by a lipase and a ruthenium complex in the presence of an acyl donor to allylic acetates of high optical purity in over 80% yield.
- Keywords
- ENZYMATIC RESOLUTION; SECONDARY ALCOHOLS; RACEMIZATION; PALLADIUM; ISOMERIZATION; KETONES
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 2, no. 15, page. 2377 - 2379, 2000-07-27
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Related Researcher
- 김만주KIM, MAHN JOO
- Dept of Chemistry