Facile synthesis of (eta(5)-Ph4C4COH)(CO)(2)RuCl and catalytic oxidation of alcohols with chloroform
SCIE
SCOPUS
- Title
- Facile synthesis of (eta(5)-Ph4C4COH)(CO)(2)RuCl and catalytic oxidation of alcohols with chloroform
- Authors
- Jung, HM; Choi, JH; Lee, SO; Kim, YH; Park, JH; Park, J
- Date Issued
- 2002-12
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A hydroxycyclopentadienyl ruthenium chloride, (eta(5)-Ph4C4COH)(CO)(2)RuCl (2), is formed quantitatively by heating the Shuo complex, {[(eta(5)-Ph4C4CO)](2)H}-Ru-2(CO)(4)(mu-H) (1) (1), in chloroform containing a stoichiometric amount of ethanol. Alcohols are oxidized by the use of 1 or 2 as the catalyst in chloroform with sodium carbonate. Secondary alcohols and primary diols are oxidized selectively to give ketones and lactones, respectively, in excellent yields.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/18790
- DOI
- 10.1021/OM020516M
- ISSN
- 0276-7333
- Article Type
- Article
- Citation
- ORGANOMETALLICS, vol. 21, no. 25, page. 5674 - 5677, 2002-12
- Files in This Item:
- There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.