Open Access System for Information Sharing

Login Library

 

Article
Cited 120 time in webofscience Cited 122 time in scopus
Metadata Downloads

A study of the mechanism of the electrochemical reaction of lithium with CoO by two-dimensional soft X-ray absorption spectroscopy (2D XAS), 2D Raman, and 2D heterospectral XAS-Raman correlation analysis SCIE SCOPUS

Title
A study of the mechanism of the electrochemical reaction of lithium with CoO by two-dimensional soft X-ray absorption spectroscopy (2D XAS), 2D Raman, and 2D heterospectral XAS-Raman correlation analysis
Authors
Choi, HCJung, YMNoda, IKim, SB
Date Issued
2003-06-19
Publisher
AMER CHEMICAL SOC
Abstract
To investigate the mechanism of the electrochemical insertion of lithium into the CoO electrode in a Li/Li-y-CoO cell, we applied a two-dimensional (2D) correlation analysis to the spectra of the LiyCoO system during the first insertion-extraction reaction as obtained by lithium concentration-dependent X-ray absorption spectroscopy (XAS) and Raman spectroscopy. 2D XAS and 2D Raman spectra yield great resolution enhancement and show that the insertion of lithium into the CoO electrode leads to Li2O formation. Moreover, by analyzing the sign of the asynchronous cross peaks, we reveal the sequence of the first insertion process: first, the intensity of the band due to CoO decreases and then that of the band due to Li2O increases. A 2D heterospectral XAS-Raman correlation analysis was also undertaken of the same XAS and Raman spectra. This heterospectral 2D correlation analysis has elucidated not only the sequence of events between XAS and Raman signals from the same species but also the correlation between the XAS and Raman bands, confirming their band assignments.
Keywords
ELECTRODE MATERIALS; METAL-OXIDES; BATTERIES; COBALT; IRON
URI
https://oasis.postech.ac.kr/handle/2014.oak/18494
DOI
10.1021/JP030438W
ISSN
1520-6106
Article Type
Article
Citation
JOURNAL OF PHYSICAL CHEMISTRY B, vol. 107, no. 24, page. 5806 - 5811, 2003-06-19
Files in This Item:
There are no files associated with this item.

qr_code

  • mendeley

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Views & Downloads

Browse