Highly Efficient and Chemoselective Ruthenium-Catalyzed Hydrosilylation of Aldehydes
SCIE
SCOPUS
- Title
- Highly Efficient and Chemoselective Ruthenium-Catalyzed Hydrosilylation of Aldehydes
- Authors
- Do, Y; Han, J; Young Ho Rhee; Park, J
- Date Issued
- 2011-12
- Publisher
- WILEY-BLACKWELL
- Abstract
- The highly chemoselective hydrosilylation of aldehydes was achieved using a ruthenium catalyst activated by a household fluorescent light (30 W) at or below room temperature. The hydrosilylation was almost exclusive to aldehydes over ketones and olefins.
- Keywords
- aldehydes; chemoselectivity; hydrosilylation; photochemistry; ruthenium complexes; DYNAMIC KINETIC RESOLUTION; BOWL-SHAPED PHOSPHANE; RACEMIZATION CATALYST; SECONDARY ALCOHOLS; CARBONYL-COMPOUNDS; HINDERED KETONES; RATE ENHANCEMENT; COMPLEXES; LIGAND; CONVENIENT
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/16818
- DOI
- 10.1002/ADSC.201100426
- ISSN
- 1615-4150
- Article Type
- Article
- Citation
- ADVANCED SYNTHESIS & CATALYSIS, vol. 353, no. 18, page. 3363 - 3366, 2011-12
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