Low Pressure Ethenolysis of Renewable Methyl Oleate in a Microchemical System
SCIE
SCOPUS
- Title
- Low Pressure Ethenolysis of Renewable Methyl Oleate in a Microchemical System
- Authors
- Park, CP; Van Wingerden, MM; Han, SY; Kim, DP; Grubbs, RH
- Date Issued
- 2011-05-06
- Publisher
- AMER CHEMICAL SOC
- Abstract
- A microchemical system for ethenolysis of renewable methyl oleate was developed, in which the dual-phase, microfluidic design enabled efficient diffusion of ethylene gas into liquid methyl oleate through an increased contact area. The increased mass transfer of ethylene favored the formation of desired commodity chemicals with significantly suppressed homometathesis when compared to the bulk system. In addition to higher selectivity and conversion, this system also provides the typical advantages of a microchemical system, including the possibility of convenient scale-up.
- Keywords
- OLEFIN METATHESIS CATALYSTS; ORGANIC-SYNTHESIS; RUTHENIUM CATALYST; FLASH CHEMISTRY; TECHNOLOGY; MICROREACTORS; CARBONYLATION; FEEDSTOCKS; REACTOR
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/16115
- DOI
- 10.1021/OL200634Y
- ISSN
- 1523-7060
- Article Type
- Article
- Citation
- ORGANIC LETTERS, vol. 13, no. 9, page. 2398 - 2401, 2011-05-06
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- There are no files associated with this item.
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