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A Dinuclear Palladium Catalyst for alpha-Hydroxylation of Carbonyls with O-2 SCIE SCOPUS
- Title
- A Dinuclear Palladium Catalyst for alpha-Hydroxylation of Carbonyls with O-2
- Authors
- Chuang, GJ; Wang, WK; Lee, E; Ritter, T
- Date Issued
- 2011-02-16
- Publisher
- American Chemical Society
- Abstract
- A chemo- and regioselective alpha-hydroxylation reaction of carbonyl compounds with molecular oxygen as oxidant is reported. The hydroxylation reaction is catalyzed by a dinuclear Pd(II) complex, which functions as an oxygen transfer catalyst, reminiscent of an oxygenase. The development of this oxidation reaction was inspired by discovery and mechanism evaluation of previously unknown Pd-(III)-Pd(III) complexes.
- Keywords
- BETA-KETO-ESTERS; MOLECULAR-OXYGEN; N-SULFONYLOXAZIRIDINES; PD(III) COMPLEXES; AEROBIC OXIDATION; DIMETHYLDIOXIRANE; SULFIDES
- ISSN
- 0002-7863
- Article Type
- Article
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 133, no. 6, page. 1760 - 1762, 2011-02-16
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Related Researcher
- 이은성LEE, EUNSUNG
- Dept of Chemistry