Rhodium-catalyzed intermolecular amidation of arenes with sulfonyl azides via chelation-assisted C-H bond activation
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SCOPUS
- Title
- Rhodium-catalyzed intermolecular amidation of arenes with sulfonyl azides via chelation-assisted C-H bond activation
- Authors
- Kim, JY; Park, SH; Ryu, J; Hwan, S; Kim, SH; Chang, S
- Date Issued
- 2012-06-06
- Publisher
- American Chemical Society
- Abstract
- We report the direct amidation of arene C-H bonds using sulfonyl azides as the amino source to release N-2 as the single byproduct. The reaction is catalyzed by a cationic rhodium complex under external oxidant-free conditions in the atmospheric environment. A broad range of chelate group-containing arenes are selectively amidated with excellent functional group tolerance, thus opening a new avenue to practical intermolecular C-N bond formation.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/14434
- DOI
- 10.1021/JA303527M
- ISSN
- 0002-7863
- Article Type
- Article
- Citation
- JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 134, no. 22, page. 9110 - 9113, 2012-06-06
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