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Raman spectroscopy study on the reactions of UV-generated oxygen atoms with single-layer graphene on SiO2/Si substrates SCIE KCI

Title
Raman spectroscopy study on the reactions of UV-generated oxygen atoms with single-layer graphene on SiO2/Si substrates
Authors
Ahn, GKim, HRHong, BHRyu, S
Date Issued
2012-01
Publisher
Korean Carbon Society
Abstract
Successful application of graphene requires development of various tools for its chemical modification. In this paper, we present a Raman spectroscopic investigation of the effects of UV light on single layer graphene with and without the presence of O-2 molecules. The UV emission from a low pressure Hg lamp photolyzes O-2 molecules into O atoms, which are known to form epoxy on the basal plane of graphene. The resulting surface epoxy groups were identified by the disorder-related Raman D band. It was also found that adhesive residues present in the graphene samples prepared by micro-mechanical exfoliation using adhesive tape severely interfere with the O atom reaction with graphene. The UV-induced reaction was also successfully applied to chemical vapor deposition-grown graphene. Since the current method can be readily carried out in ambient air only with UV light, it will be useful in modifying the surfaces of graphene and related materials.
URI
https://oasis.postech.ac.kr/handle/2014.oak/13556
DOI
10.5714/CL.2012.13.1.034
ISSN
1976-4251
Article Type
Article
Citation
CARBON LETTERS, vol. 13, no. 1, page. 34 - 38, 2012-01
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류순민RYU, SUNMIN
Dept of Chemistry
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