Dual-channel charge transfer doping of graphene by sulfuric acid
SCIE
SCOPUS
KCI
- Title
- Dual-channel charge transfer doping of graphene by sulfuric acid
- Authors
- Park, Kwanghee; Ryu, Sunmin
- Date Issued
- 2022-01
- Publisher
- John Wiley and Sons Inc
- Abstract
- © 2021 Korean Chemical Society, Seoul & Wiley-VCH GmbHTwo-dimensional materials represented by graphene and transition metal dichalcogenides undergo charge transfer (CT) processes and become hole-doped in strong mineral acids. Nonetheless, their mechanisms remain unclear or controversial. This work proposes and verifies two distinctive CT channels in sulfuric acids, respectively, driven by oxygen reduction reaction involving O2/H2O redox couples and reduction of bisulfate or related species. Acid-induced changes in the charge density of graphene were in situ quantified as a function of oxygen content using Raman spectroscopy. At acid concentrations lower than 6 M, the former channel is operative, requiring dissolved O2. Above 6 M, the degree of CT was even higher because the former is cooperated with by the latter channel, which does not need dissolved oxygen. The mechanism revealed in this study will advance our fundamental understanding of how low-dimensional materials interact with chemical environments.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/113250
- DOI
- 10.1002/bkcs.12443
- ISSN
- 0253-2964
- Article Type
- Article
- Citation
- Bulletin of the Korean Chemical Society, vol. 43, no. 1, page. 40 - 43, 2022-01
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