Open Access System for Information Sharing

Login Library

 

Article
Cited 57 time in webofscience Cited 57 time in scopus
Metadata Downloads

Fluorobenzene and p-difluorobenzene microsolvated by methanol: An infrared spectroscopic and ab initio theoretical investigation SCIE SCOPUS

Title
Fluorobenzene and p-difluorobenzene microsolvated by methanol: An infrared spectroscopic and ab initio theoretical investigation
Authors
Buchhold, KReimann, BDjafari, SBarth, HDBrutschy, BTarakeshwar, PKim, KS
Date Issued
2000-01-22
Publisher
AMER INST PHYSICS
Abstract
Laser spectroscopy, i.e., resonant two-photon ionization (R2PI), IR/R2PI ion depletion and hole burning spectroscopy have been applied in an experimental study of heterogenous clusters consisting of fluorobenzene (FB) or p-difluorobenzene (pDFB), respectively, microsolvated by up to three methanol molecules. Their infrared ion depletion spectra were taken in the region of the OH and CH stretches of methanol. In these complexes the methanol molecules form subclusters, which are weakly hydrogen bonded to either the aromatic pi-system (pi(OH)) or to the fluorine substituent (sigma(F)) and a CH group (sigma(CH)). In FB .(MeOH)(1), pDFB .(MeOH)(1), pDFB .(MeOH)(2) and one isomer of FB .(MeOH)(2) the methanol subunits exclusively exhibit sigma(F) and sigma(CH) H-bonds. A further isomer of FB .(MeOH)(2) exhibits a pi(OH) type interaction. For FB .(MeOH)(3) and pDFB .(MeOH)(3) (1:3) complexes the methanol subcluster may take on either a chainlike or a ringlike conformation. In the chainlike isomer of FB .(MeOH)(3) the methanol trimer interacts with the chromophore via a pi(OH) H-bond while with the corresponding pDFB cluster a sigma(F) H-bond is formed. High level ab initio calculations, still feasible for molecular clusters of this size, have also been carried out to supplement the experimental investigations. These calculations include complete geometry optimizations of FB .(MeOH)(n) (n = 1-2) and pDFB .(MeOH)(1) at the MP2/6-31 + G* and B3LYP/6-31 + G* levels of theory. The minimum energy structures of the microsolvates together with their harmonic vibrational spectra allow a reliable assignment of the experimentally observed spectra and the determination of structure of the complexes. (C) 2000 American Institute of Physics. [S0021-9606(00)01804-3].
URI
https://oasis.postech.ac.kr/handle/2014.oak/10756
DOI
10.1063/1.480748
ISSN
0021-9606
Article Type
Article
Citation
JOURNAL OF CHEMICAL PHYSICS, vol. 112, no. 4, page. 1844 - 1858, 2000-01-22
Files in This Item:

qr_code

  • mendeley

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Views & Downloads

Browse