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Effects of transformation-induced plasticity (TRIP) on tensile property improvement of Fe45Co30Cr10V10Ni5-xMnx high-entropy alloys

Title
Effects of transformation-induced plasticity (TRIP) on tensile property improvement of Fe45Co30Cr10V10Ni5-xMnx high-entropy alloys
Authors
Yang, JunhaJo, Yong HeeKim, Dae WoongChoi, Won-MiKim, Hyoung SeopLee, Byeong-JooSohn, Seok SuLee, Sunghak
Date Issued
2020-01
Publisher
ELSEVIER SCIENCE SA
Abstract
A new metastable high-entropy alloy (HEA) system was suggested by thermodynamic calculations based on the Gibbs free energies of FCC and HCP and the associated stacking fault energy (SFE). The Fe45Co30Cr10V10Ni5-xMnx (x = 0, 2.5, and 5 at.%) alloys were fabricated, and their tensile properties were evaluated at room and cryogenic temperatures. The relationship between the deformation mechanism and strain hardening behavior was investigated to reveal the role of deformation-induced martensitic transformation on tensile properties. The difference in Gibbs energy decreases with increasing Mn content, leading to the decreased SFE in sequence. At room temperature, similar to 60% of BCC martensite in the SUM HEA contributes effectively to the steady strain hardening, suppressing the plastic instability. This TRIP effect achieves much eminence in the cryogenic deformation, enabling the tensile strength to reach over 1.6 GPa due to 100% of BCC and HCP martensite. In addition to the fraction of martensite, the increased Mn content reduces a critical strain required to trigger the martensitic transformation and then raises the transformation rate. The present findings may provide a guide for the design of metastable HEAs to enhance tensile properties for cryogenic applications through adjusting SFE and TRIP effect.
Keywords
Chromium alloys; Cobalt alloys; Cryogenics; Deformation; Entropy; Gibbs free energy; High-entropy alloys; Iron alloys; Manganese; Martensite; Plasticity; Stacking faults; Strain hardening; Tensile strength; Cryogenic applications; Cryogenic temperatures; Deformation mechanism; Plastic instabilities; Stacking fault energies; Strain hardening behavior; Thermodynamic calculations; Transformation induced plasticity; Martensitic transformations
URI
https://oasis.postech.ac.kr/handle/2014.oak/101875
ISSN
0921-5093
Article Type
Article
Citation
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, vol. 772, 2020-01
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이성학LEE, SUNG HAK
Dept of Materials Science & Enginrg
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