DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Yonghwi | - |
dc.contributor.author | Haldar, Ritesh | - |
dc.contributor.author | Kim, Hyunuk | - |
dc.contributor.author | Koo, Jaehyoung | - |
dc.contributor.author | Kim, Kimoon | - |
dc.date.accessioned | 2019-04-07T20:00:32Z | - |
dc.date.available | 2019-04-07T20:00:32Z | - |
dc.date.created | 2018-01-24 | - |
dc.date.issued | 2016-01 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/96322 | - |
dc.description.abstract | The guest-dependent thermal response of the flexible MOF Zn-2(BDC)(2)(DABCO) (1) has been studied. A series of temperature-dependent single crystallographic analyses revealed inherent structural thermal responses of 1. The guest-free framework 1 exhibited interesting thermal responses including anisotropic thermal expansion (negative thermal expansion (NTE) along the a- and b-axes, positive thermal expansion (PTE) along the c-axis) and disorder-order phase transition. In addition, inclusion of guest molecules (DMF and benzene) brought distinct thermal responses to 1 from host-guest interactions. 1.4DMF showed altered thermal responses, presenting disorder-order phase transitions at a higher temperature and PTE along the a- and b-axes. Meanwhile, 1.3benzene displayed a quite different type of thermal response such as a hinge like motion (breathing) without a symmetry change. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | DALTON TRANSACTIONS | - |
dc.title | The guest-dependent thermal response of the flexible MOF Zn-2(BDC)(2)(DABCO) | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c5dt03710g | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, v.45, no.10, pp.4187 - 4192 | - |
dc.identifier.wosid | 000371710500016 | - |
dc.citation.endPage | 4192 | - |
dc.citation.number | 10 | - |
dc.citation.startPage | 4187 | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.citation.volume | 45 | - |
dc.contributor.affiliatedAuthor | Koo, Jaehyoung | - |
dc.contributor.affiliatedAuthor | Kim, Kimoon | - |
dc.identifier.scopusid | 2-s2.0-84959571863 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | METAL-ORGANIC FRAMEWORK | - |
dc.subject.keywordPlus | POROUS COORDINATION POLYMER | - |
dc.subject.keywordPlus | X-RAY-DIFFRACTION | - |
dc.subject.keywordPlus | PEROVSKITE ARCHITECTURE | - |
dc.subject.keywordPlus | HYDROGEN-BOND | - |
dc.subject.keywordPlus | EXPANSION | - |
dc.subject.keywordPlus | NANOINDENTATION | - |
dc.subject.keywordPlus | TRANSFORMATION | - |
dc.subject.keywordPlus | SEPARATIONS | - |
dc.subject.keywordPlus | TEMPERATURE | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.