DC Field | Value | Language |
---|---|---|
dc.contributor.author | KIM, HYE SUNG | - |
dc.contributor.author | JANG, AHREUM | - |
dc.contributor.author | CHOI, SI YOUNG | - |
dc.contributor.author | JUNG, WOOCHUL | - |
dc.contributor.author | CHUNG, SUNG YOON | - |
dc.date.accessioned | 2019-04-07T19:57:16Z | - |
dc.date.available | 2019-04-07T19:57:16Z | - |
dc.date.created | 2019-03-11 | - |
dc.date.issued | 2016-10-17 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/96279 | - |
dc.description.abstract | In most proton-conducing perovskite oxides, the electrostatic attraction between negatively charged acceptor dopants and protonic defects having a positive charge is known to be a major cause of retardation of proton conduction, a phenomenon that is generally referred to as proton trapping. We experimentally show that proton trapping can be suppressed by clustering of positively charged oxygen vacancies to acceptors in BaZrO3- and BaCeO3-. In particular, to ensure the vacancy-acceptor association is effective against proton trapping, the valence electron density of acceptors should not significantly vary when the oxygen vacancies cluster, based on the weak hybridization between the valence d or p orbitals of acceptors and the 2p orbitals of oxygen. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.title | Vacancy-Induced Electronic Structure Variation of Acceptors and Correlation with Proton Conduction in Perovskite Oxides | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.201603835 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.43, pp.13499 - 13503 | - |
dc.identifier.wosid | 000385718300023 | - |
dc.citation.endPage | 13503 | - |
dc.citation.number | 43 | - |
dc.citation.startPage | 13499 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 55 | - |
dc.contributor.affiliatedAuthor | CHOI, SI YOUNG | - |
dc.identifier.scopusid | 2-s2.0-84981717686 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | DOPED BARIUM ZIRCONATE | - |
dc.subject.keywordPlus | HIGH-TEMPERATURE | - |
dc.subject.keywordPlus | FUEL-CELLS | - |
dc.subject.keywordPlus | PRINCIPLES | - |
dc.subject.keywordPlus | MOBILITY | - |
dc.subject.keywordPlus | CRYSTAL | - |
dc.subject.keywordAuthor | defects | - |
dc.subject.keywordAuthor | electronic structure | - |
dc.subject.keywordAuthor | perovskite phases | - |
dc.subject.keywordAuthor | proton conduction | - |
dc.subject.keywordAuthor | vacancies | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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