DC Field | Value | Language |
---|---|---|
dc.contributor.author | Seo, Seungwan | - |
dc.contributor.author | Yang, Taimin | - |
dc.contributor.author | Shin, Jiho | - |
dc.contributor.author | Jo, Donghui | - |
dc.contributor.author | Zou, Xiaodong | - |
dc.contributor.author | Hong, Suk Bong | - |
dc.date.accessioned | 2019-04-07T17:57:34Z | - |
dc.date.available | 2019-04-07T17:57:34Z | - |
dc.date.created | 2018-07-20 | - |
dc.date.issued | 2018-03 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/95937 | - |
dc.description.abstract | Herein we report the synthesis and structures of two new small-pore aluminophosphate molecular sieves PST-13 and PST-14 with mutually connected 8-ring channels. The structure of PST-13, synthesized using diethylamine as an organic structure-directing agent, contains penta-coordinated framework Al atoms bridged by hydroxy groups and thus edge-sharing 3- and 5-rings. Upon calcination, PST-13 undergoes a transformation to PST-14 with loss of bridging hydroxy groups and occluded organic species. The structures of both materials consist nonjointly of pairs of previously undiscovered 1,5- and 1,6-open double 4-rings (d4rs) which are mirror images of each other. We also present a series of novel chemically feasible hypothetical structures built from 1-open d4r (sti) or 1,3-open d4r (nsc) units, as well as from these two enantiomeric structural building units. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.title | Two Aluminophosphate Molecular Sieves Built from Pairs of Enantiomeric Structural Building Units | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/anie.201800791 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.57, no.14, pp.3727 - 3732 | - |
dc.identifier.wosid | 000428350100033 | - |
dc.citation.endPage | 3732 | - |
dc.citation.number | 14 | - |
dc.citation.startPage | 3727 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 57 | - |
dc.contributor.affiliatedAuthor | Hong, Suk Bong | - |
dc.identifier.scopusid | 2-s2.0-85043247545 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | ROTATION ELECTRON-DIFFRACTION | - |
dc.subject.keywordPlus | CRYSTALLINE INORGANIC SOLIDS | - |
dc.subject.keywordPlus | FRAMEWORKS | - |
dc.subject.keywordPlus | GEOMETRY | - |
dc.subject.keywordAuthor | aluminophosphates | - |
dc.subject.keywordAuthor | enantiomeric structural building units | - |
dc.subject.keywordAuthor | microporous materials | - |
dc.subject.keywordAuthor | structure elucidation | - |
dc.subject.keywordAuthor | zeolites | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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