DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kim, Minjun | - |
dc.contributor.author | Park, Won-Tae | - |
dc.contributor.author | Park, Sang Ah | - |
dc.contributor.author | Park, Cheol Woong | - |
dc.contributor.author | Ryu, Seung Un | - |
dc.contributor.author | Lee, DaeHwan | - |
dc.contributor.author | Noh, Yong-Young | - |
dc.contributor.author | PARK, TAI HO | - |
dc.date.accessioned | 2019-04-07T14:57:26Z | - |
dc.date.available | 2019-04-07T14:57:26Z | - |
dc.date.created | 2019-03-11 | - |
dc.date.issued | 2019-03-07 | - |
dc.identifier.issn | 1616-301X | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/95260 | - |
dc.description.abstract | A molecular design strategy to achieve highly balanced ambipolar charge transport for donor-acceptor (D-A) isoindigo (IIG)-based copolymer through systematic selection of fluorination positions is reported. To study fluorine substitution site effects on electronic and structural properties, two fluorinated IIG-based copolymers (PIIG-iFT2 and PIIG-oFT2) are synthesized, which contain two fluorine atoms at the bithiophene (T2) inner and outer site and compare them with a nonfluorinated copolymer of IIG and T2 (PIIG-T2) as the reference polymer. Fluorination at the outer site of T2 in PIIG-oFT2 polymer effectively lowers molecular energy levels and increases molecular planarity more than fluorination at the T2 inner site. PIIG-oFT2 organic field-effect transistors show highly balanced ambipolar mobility, hole mobility (mu(h))/electron mobility (mu(e)) = 1 by increasing electron mobility, whereas PIIG-T2 (mu(h)/mu(e) = 9.0) and PIIG-iFT2 (mu(h)/mu(e) = 2.4) exhibit unbalanced ambipolar transport. The ambipolar complementary-like inverter is also demonstrated by simple one-time coating of PIIG-oFT2 with gain = 21. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ADVANCED FUNCTIONAL MATERIALS | - |
dc.subject | THIN-FILM TRANSISTORS | - |
dc.subject | DERIVATIVES | - |
dc.subject | SEMICONDUCTORS | - |
dc.subject | CONFORMATION | - |
dc.title | Controlling Ambipolar Charge Transport in Isoindigo-Based Conjugated Polymers by Altering Fluorine Substitution Position for High-Performance Organic Field-Effect Transistors | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/adfm.201805994 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ADVANCED FUNCTIONAL MATERIALS, v.29, no.10 | - |
dc.identifier.wosid | 000460474200008 | - |
dc.citation.number | 10 | - |
dc.citation.title | ADVANCED FUNCTIONAL MATERIALS | - |
dc.citation.volume | 29 | - |
dc.contributor.affiliatedAuthor | Noh, Yong-Young | - |
dc.contributor.affiliatedAuthor | PARK, TAI HO | - |
dc.identifier.scopusid | 2-s2.0-85060568846 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | ambipolar polymer, fluorination | - |
dc.subject.keywordPlus | inverter, isoindigo-based polymer,organic field-effect transistor | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Nanoscience & Nanotechnology | - |
dc.relation.journalWebOfScienceCategory | Materials Science, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Physics, Applied | - |
dc.relation.journalWebOfScienceCategory | Physics, Condensed Matter | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
dc.relation.journalResearchArea | Materials Science | - |
dc.relation.journalResearchArea | Physics | - |
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