DC Field | Value | Language |
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dc.contributor.author | Jo, Donghui | - |
dc.contributor.author | Mayoral, Alavro | - |
dc.contributor.author | Hong, Suk Bong | - |
dc.contributor.author | Camblor, Miguel A. | - |
dc.date.accessioned | 2018-06-15T05:28:45Z | - |
dc.date.available | 2018-06-15T05:28:45Z | - |
dc.date.created | 2017-12-21 | - |
dc.date.issued | 2017-03 | - |
dc.identifier.issn | 1434-1948 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/50518 | - |
dc.description.abstract | HPM-5, a porous aluminosilicate with an intricate and so far unsolved structure, has been synthesized by using 1,2,3-trimethylimidazolium in hydroxide medium in the absence of fluoride anions. It consistently displays an ill-defined XRD pattern with broad and overlapped reflections and contains a large concentration of defects, as evidenced by IR and 29Si MAS NMR spectroscopy. 1H MAS NMR spectroscopy confirmed the existence of highly deshielded protons (delta = -11.6 ppm) assigned to hydrogen atoms in relatively strong Si-O-H---O-Si hydrogen bonds (O---O distance = 2.64 A) The calcined material shows limited microporosity (0.07-0.09 cm3 g-1). The results of a high-resolution transmission electron microscopy study suggest HPM-5 may be far more complicated than "standard" layered zeolites and may consist of low-density layers profusely decorated by holes. The resulting lace-like layers may be too unstable to withstand reactions characteristic of more conventional layered materials (both delamination and expansion by silylation); although the derivatives show an increase in the specific surface area, the layers are apparently disassembled and, at most, only ribbons remain. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.title | On the Porous Silicate HPM-5 | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/ejic.201700023 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, v.2017, no.19, pp.2525 - 2531 | - |
dc.identifier.wosid | 000403050300002 | - |
dc.date.tcdate | 2018-03-23 | - |
dc.citation.endPage | 2531 | - |
dc.citation.number | 19 | - |
dc.citation.startPage | 2525 | - |
dc.citation.title | EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | - |
dc.citation.volume | 2017 | - |
dc.contributor.affiliatedAuthor | Hong, Suk Bong | - |
dc.identifier.scopusid | 2-s2.0-85019546276 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | HYDROUS LAYER SILICATE | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | TOPOTACTIC CONDENSATION | - |
dc.subject.keywordPlus | ADSORPTION PROPERTIES | - |
dc.subject.keywordPlus | DELAMINATED ZEOLITE | - |
dc.subject.keywordPlus | STRUCTURE-DIRECTION | - |
dc.subject.keywordPlus | LAMELLAR PRECURSOR | - |
dc.subject.keywordPlus | MOLECULAR-SIEVE | - |
dc.subject.keywordPlus | ITQ-12 | - |
dc.subject.keywordPlus | ITW | - |
dc.subject.keywordAuthor | Zeolites | - |
dc.subject.keywordAuthor | Zeolite analogues | - |
dc.subject.keywordAuthor | Silicates | - |
dc.subject.keywordAuthor | Microporous materials | - |
dc.subject.keywordAuthor | Nanostructures | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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