DC Field | Value | Language |
---|---|---|
dc.contributor.author | Bae, J | - |
dc.contributor.author | Cho, J | - |
dc.contributor.author | Lee, JH | - |
dc.contributor.author | Seo, SM | - |
dc.contributor.author | Hong, SB | - |
dc.date.accessioned | 2017-07-19T13:56:16Z | - |
dc.date.available | 2017-07-19T13:56:16Z | - |
dc.date.created | 2017-02-28 | - |
dc.date.issued | 2016-06-20 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/37892 | - |
dc.description.abstract | Zeolite EU-12, the framework structure of which has remained unsolved during the past 30 years, is synthesized at a specific SiO2/Al2O3 ratio using choline as an organic structure-directing agent, with both Na+ and Rb+ ions present. Synchrotron powder X-ray diffraction and Rietveld analyses reveal that the EU-12 structure has a two-dimensional 8-ring channel system. Among the two distinct 8-ring (4.6 x 2.8 and 5.0 x 2.7 angstrom) channels along c axis, the smaller one interconnects with the sinusoidal 8-ring (4.8 x 3.3 angstrom) channel along a axis. The other large one is simply linked up with the sinusoidal channel by sharing 8-rings (4.8 x 2.6 angstrom) in the ac plane. The proton form of EU-12 was found to show a considerably higher ethene selectivity in the low-temperature dehydration of ethanol than H-mordenite, the best catalyst for this reaction. | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.title | EU-12: A Small-Pore High-Silica Zeolite Containing Sinusoidal Eight-Ring Channels | - |
dc.type | Article | - |
dc.identifier.doi | 10.1002/ANIE.201600146 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.26, pp.7369 - 7373 | - |
dc.identifier.wosid | 000383077400006 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 7373 | - |
dc.citation.number | 26 | - |
dc.citation.startPage | 7369 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 55 | - |
dc.contributor.affiliatedAuthor | Hong, SB | - |
dc.identifier.scopusid | 2-s2.0-84975068312 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 10 | - |
dc.description.scptc | 4 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CATALYTIC BEHAVIOR | - |
dc.subject.keywordPlus | DEHYDRATION | - |
dc.subject.keywordPlus | ETHANOL | - |
dc.subject.keywordAuthor | aluminosilicates | - |
dc.subject.keywordAuthor | ethanol dehydration | - |
dc.subject.keywordAuthor | microporous materials | - |
dc.subject.keywordAuthor | structure elucidation | - |
dc.subject.keywordAuthor | zeolites | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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