DC Field | Value | Language |
---|---|---|
dc.contributor.author | Choi, YK | - |
dc.contributor.author | Kim, Y | - |
dc.contributor.author | Han, K | - |
dc.contributor.author | Park, J | - |
dc.contributor.author | Kim, MJ | - |
dc.date.accessioned | 2016-04-01T03:15:25Z | - |
dc.date.available | 2016-04-01T03:15:25Z | - |
dc.date.created | 2010-03-22 | - |
dc.date.issued | 2009-12-18 | - |
dc.identifier.issn | 0022-3263 | - |
dc.identifier.other | 2009-OAK-0000020445 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/26444 | - |
dc.description.abstract | The complete conversion of racemic amino acid amides to optically active amino acid derivatives was accomplished via lipase/palladium-catalyzed dynamic kinetic resolution (DKR). In the DKR, a lipase catalyzes the selective acylation Of L-substrate in the presence of acyl donor while unreacted D-substrate is isomerized by a Pd nanocatalyst to L-substrate. The DKR reactions provided good yields (80-98%) and high enantiomeric excess (95-98% ee). Interestingly, the DKR reactions of phenylglycine amide in the presence of Z-Gly-OMe or Z-Gly-Gly-OMe yielded optically active di- and tripeptide. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.subject | ENANTIOMERICALLY PURE AMINES | - |
dc.subject | SECONDARY-AMINES | - |
dc.subject | CHIRAL AMINES | - |
dc.subject | RACEMIZATION | - |
dc.subject | CATALYSTS | - |
dc.subject | PALLADIUM | - |
dc.subject | ALCOHOLS | - |
dc.subject | LIPASE | - |
dc.subject | EFFICIENT | - |
dc.subject | ENZYMES | - |
dc.title | Synthesis of Optically Active Amino Acid Derivatives via Dynamic Kinetic Resolution | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1021/JO902034X | - |
dc.author.google | Choi, YK | - |
dc.author.google | Kim, Y | - |
dc.author.google | Han, K | - |
dc.author.google | Park, J | - |
dc.author.google | Kim, MJ | - |
dc.relation.volume | 74 | - |
dc.relation.issue | 24 | - |
dc.relation.startpage | 9543 | - |
dc.relation.lastpage | 9545 | - |
dc.contributor.id | 10075891 | - |
dc.relation.journal | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF ORGANIC CHEMISTRY, v.74, no.24, pp.9543 - 9545 | - |
dc.identifier.wosid | 000272462100046 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 9545 | - |
dc.citation.number | 24 | - |
dc.citation.startPage | 9543 | - |
dc.citation.title | JOURNAL OF ORGANIC CHEMISTRY | - |
dc.citation.volume | 74 | - |
dc.contributor.affiliatedAuthor | Park, J | - |
dc.contributor.affiliatedAuthor | Kim, MJ | - |
dc.identifier.scopusid | 2-s2.0-73149087689 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 30 | - |
dc.description.scptc | 31 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | ENANTIOMERICALLY PURE AMINES | - |
dc.subject.keywordPlus | SECONDARY-AMINES | - |
dc.subject.keywordPlus | CHIRAL AMINES | - |
dc.subject.keywordPlus | RACEMIZATION | - |
dc.subject.keywordPlus | CATALYSTS | - |
dc.subject.keywordPlus | PALLADIUM | - |
dc.subject.keywordPlus | ALCOHOLS | - |
dc.subject.keywordPlus | LIPASE | - |
dc.subject.keywordPlus | EFFICIENT | - |
dc.subject.keywordPlus | ENZYMES | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
library@postech.ac.kr Tel: 054-279-2548
Copyrights © by 2017 Pohang University of Science ad Technology All right reserved.