DC Field | Value | Language |
---|---|---|
dc.contributor.author | Chul Hoon Kim | - |
dc.contributor.author | Jaehun Park | - |
dc.contributor.author | Jangwon Seo | - |
dc.contributor.author | Soo Young Park | - |
dc.contributor.author | Joo, T | - |
dc.date.accessioned | 2016-04-01T02:54:48Z | - |
dc.date.available | 2016-04-01T02:54:48Z | - |
dc.date.created | 2010-05-07 | - |
dc.date.issued | 2010-05-13 | - |
dc.identifier.issn | 1089-5639 | - |
dc.identifier.other | 2010-OAK-0000021201 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/25973 | - |
dc.description.abstract | Excited state intramolecular proton transfer (ESIPT) and subsequent intramolecular charge transfer (ICT) dynamics of a 2-(2'-hydroxyphenyl)benzoxazole derivative conjugated with an electron withdrawing group (HBOCE) in solutions and a polymer film has been investigated by femtosecond time-resolved fluorescence (TRF) and TRF spectra measurements without the conventional spectral reconstruction method. TRF with high enough resolution (<100 fs) reveals that the ESIPT dynamics of HBOCE in liquids proceeds by at least two time constants of similar to 250 fs and similar to 1.2 ps. The relative amplitude of the slower picosecond component is smaller in the polymer film than that in solution. Conformational heterogeneity in the ground state originating from the dispersion of the dihedral angle between the phenolic and benzoxazole groups is invoked to account for the dispersive ESIPT dynamics in liquids. From the TRF spectra of both the enol and keto isomers, we have identified the ICT reaction of the keto isomer occurring subsequent to the ESIPT. The ICT proceeds also by two time constants of near instantaneous and 2.7 ps. Since the ICT dynamics of HBOCE is rather close to the polar solvation dynamics, we argue that the ICT is barrierless and determined mostly by the solvent fluctuation. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | American Chemical Society | - |
dc.relation.isPartOf | JOURNAL OF PHYSICAL CHEMISTRY A | - |
dc.subject | FLUORESCENCE UP-CONVERSION | - |
dc.subject | TIME-RESOLVED FLUORESCENCE | - |
dc.subject | POTENTIAL-ENERGY SURFACES | - |
dc.subject | FEMTOSECOND DYNAMICS | - |
dc.subject | ELECTRON-TRANSFER | - |
dc.subject | SOLVATION DYNAMICS | - |
dc.subject | HYDROGEN-TRANSFER | - |
dc.subject | STOKES SHIFT | - |
dc.subject | ESIPT | - |
dc.subject | SPECTROSCOPY | - |
dc.title | Excited state intramolecular proton transfer and subsequent charge transfer dynamics of a 2-(2′-hydroxyphenyl)benzoxazole derivative in solution | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1021/jp909438p | - |
dc.author.google | Kim, CH | - |
dc.author.google | Park, J | - |
dc.author.google | Seo, J | - |
dc.author.google | Park, SY | - |
dc.author.google | Joo, T | - |
dc.relation.volume | 114 | - |
dc.relation.issue | 18 | - |
dc.contributor.id | 10092693 | - |
dc.relation.journal | JOURNAL OF PHYSICAL CHEMISTRY A | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY A, v.114, no.18, pp.5618 - 5629 | - |
dc.identifier.wosid | 000277280400002 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 5629 | - |
dc.citation.number | 18 | - |
dc.citation.startPage | 5618 | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY A | - |
dc.citation.volume | 114 | - |
dc.contributor.affiliatedAuthor | Joo, T | - |
dc.identifier.scopusid | 2-s2.0-77952212872 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 82 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | FLUORESCENCE UP-CONVERSION | - |
dc.subject.keywordPlus | TIME-RESOLVED FLUORESCENCE | - |
dc.subject.keywordPlus | POTENTIAL-ENERGY SURFACES | - |
dc.subject.keywordPlus | FEMTOSECOND DYNAMICS | - |
dc.subject.keywordPlus | ELECTRON-TRANSFER | - |
dc.subject.keywordPlus | SOLVATION DYNAMICS | - |
dc.subject.keywordPlus | HYDROGEN-TRANSFER | - |
dc.subject.keywordPlus | STOKES SHIFT | - |
dc.subject.keywordPlus | ESIPT | - |
dc.subject.keywordPlus | SPECTROSCOPY | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.relation.journalWebOfScienceCategory | Physics, Atomic, Molecular & Chemical | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Physics | - |
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