DC Field | Value | Language |
---|---|---|
dc.contributor.author | Oh, WS | - |
dc.contributor.author | Chung, TD | - |
dc.contributor.author | Kim, J | - |
dc.contributor.author | Kim, HS | - |
dc.contributor.author | Kim, H | - |
dc.contributor.author | Hwang, D | - |
dc.contributor.author | Kim, K | - |
dc.contributor.author | Rha, SG | - |
dc.contributor.author | Choe, JI | - |
dc.contributor.author | Chang, SK | - |
dc.date.accessioned | 2016-03-31T13:47:57Z | - |
dc.date.available | 2016-03-31T13:47:57Z | - |
dc.date.created | 2009-03-20 | - |
dc.date.issued | 1998-01 | - |
dc.identifier.issn | 1061-0278 | - |
dc.identifier.other | 1998-OAK-0000000470 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/20607 | - |
dc.description.abstract | Calix[4]arene-based monoquinones having three efficient ligating groups of alkoxycarbomethyl ethers were prepared and their ionophoric properties were investigated by electrochemical technique. Calix[4]-triester-monoquinones 3a and 3b were prepared from calix[4]arene and p-tert-butylcalix[4]arene by the selective trialkylation followed by oxidation with Tl(NO3)(3) and Tl(CF3CO2)(3), respectively. X-ray crystal structural analysis revealed that the ligand 3a adopted a partial cone conformation with an anti quinone moiety. MM+ calculations suggested that the energy difference between the two conformations is relatively small (<3.5 kcal mole(-1)). Electrochemical studies also showed that the monoquinones 3a and 3b form strong complexes with Na+ ion, and the positive shifts in the reduction potential exceeded those of the closely related diquiones 5a and 5b. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | GORDON BREACH SCI PUBL LTD | - |
dc.relation.isPartOf | SUPRAMOLECULAR CHEMISTRY | - |
dc.subject | calix[4]arene | - |
dc.subject | monoquinone | - |
dc.subject | Na+ ion | - |
dc.subject | ionophore | - |
dc.subject | electrochemistry | - |
dc.subject | CATION-BINDING PROPERTIES | - |
dc.subject | CALIX<4>ARENE | - |
dc.subject | RECOGNITION | - |
dc.subject | CALIXARENES | - |
dc.subject | SELECTIVITY | - |
dc.subject | AMMONIUM | - |
dc.subject | METAL | - |
dc.subject | REDOX | - |
dc.subject | CALIX<4>QUINONES | - |
dc.subject | CALIXQUINONES | - |
dc.title | Synthesis and electrochemical properties of calix[4]arene-triester-monoquinones | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1080/10610279808034990 | - |
dc.author.google | Oh, WS | - |
dc.author.google | Chung, TD | - |
dc.author.google | Kim, J | - |
dc.author.google | Kim, HS | - |
dc.author.google | Kim, H | - |
dc.author.google | Hwang, D | - |
dc.author.google | Kim, K | - |
dc.author.google | Rha, SG | - |
dc.author.google | Choe, JI | - |
dc.author.google | Chang, SK | - |
dc.relation.volume | 9 | - |
dc.relation.issue | 3 | - |
dc.relation.startpage | 221 | - |
dc.relation.lastpage | 229 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | SUPRAMOLECULAR CHEMISTRY | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | SUPRAMOLECULAR CHEMISTRY, v.9, no.3, pp.221 - 229 | - |
dc.identifier.wosid | 000076775200009 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 229 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 221 | - |
dc.citation.title | SUPRAMOLECULAR CHEMISTRY | - |
dc.citation.volume | 9 | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-0012369870 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 3 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CATION-BINDING PROPERTIES | - |
dc.subject.keywordPlus | CALIX<4>ARENE | - |
dc.subject.keywordPlus | RECOGNITION | - |
dc.subject.keywordPlus | CALIXARENES | - |
dc.subject.keywordPlus | SELECTIVITY | - |
dc.subject.keywordPlus | AMMONIUM | - |
dc.subject.keywordPlus | METAL | - |
dc.subject.keywordPlus | REDOX | - |
dc.subject.keywordPlus | CALIX<4>QUINONES | - |
dc.subject.keywordPlus | CALIXQUINONES | - |
dc.subject.keywordAuthor | calix[4]arene | - |
dc.subject.keywordAuthor | monoquinone | - |
dc.subject.keywordAuthor | Na+ ion | - |
dc.subject.keywordAuthor | ionophore | - |
dc.subject.keywordAuthor | electrochemistry | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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