DC Field | Value | Language |
---|---|---|
dc.contributor.author | Casey, CP | - |
dc.contributor.author | Bikzhanova, GA | - |
dc.contributor.author | Backvall, JE | - |
dc.contributor.author | Johansson, L | - |
dc.contributor.author | Park, J | - |
dc.contributor.author | Kim, YH | - |
dc.date.accessioned | 2016-03-31T13:06:54Z | - |
dc.date.available | 2016-03-31T13:06:54Z | - |
dc.date.created | 2009-03-16 | - |
dc.date.issued | 2002-04-29 | - |
dc.identifier.issn | 0276-7333 | - |
dc.identifier.other | 2002-OAK-0000002610 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/19102 | - |
dc.description.abstract | The reaction of [2,3,4,5-Ph-4(eta(4)-C4CO)]Ru(CO)(3) (5a) with Na2CO3 in aqueous acetone followed by low-temperature treatment with NH4Cl was reported to give the material A, which was formulated as the isopropyl alcohol complex [2,3,4,5-Ph-4(eta(4)-C4CO)](CO)(2)Ru(HOCHMe2) (3a). Reinvestigation of this reaction indicates that A is instead the isopropylamine complex [2,3,4,5-Ph-4(eta(4)-C4CO)](CO)(2)Ru(H2NCHMe2) (4a). The formation of 4a is proposed to occur by formation of the imine of acetone followed by reduction of the imine by the (hydroxycyclopentadienyl)ruthenium hydride [2,3,4,5-Ph-4(eta(5)-C4COH)]Ru(CO)(2)H (2a) formed in the reaction of 5a with Na2CO3 in aqueous acetone and subsequent acidification with aqueous NH4Cl. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | ORGANOMETALLICS | - |
dc.subject | DYNAMIC KINETIC RESOLUTION | - |
dc.subject | RUTHENIUM COMPLEXES | - |
dc.subject | SECONDARY ALCOHOLS | - |
dc.subject | HYDROGEN-TRANSFER | - |
dc.subject | CATALYSIS | - |
dc.subject | HYDRIDE | - |
dc.subject | ACID | - |
dc.title | Unexpected formation of the isopropylamine complex [2,3,4,5-Ph-4(eta(4)-C4CO)](CO)(2)Ru(H2NCHMe2) in the attempted synthesis of an isopropyl alcohol complex | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | - |
dc.identifier.doi | 10.1021/OM020097T | - |
dc.author.google | Casey, CP | - |
dc.author.google | Bikzhanova, GA | - |
dc.author.google | Backvall, JE | - |
dc.author.google | Johansson, L | - |
dc.author.google | Park, J | - |
dc.author.google | Kim, YH | - |
dc.relation.volume | 21 | - |
dc.relation.issue | 9 | - |
dc.relation.startpage | 1955 | - |
dc.relation.lastpage | 1959 | - |
dc.contributor.id | 10075891 | - |
dc.relation.journal | ORGANOMETALLICS | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ORGANOMETALLICS, v.21, no.9, pp.1955 - 1959 | - |
dc.identifier.wosid | 000175369600030 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 1959 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 1955 | - |
dc.citation.title | ORGANOMETALLICS | - |
dc.citation.volume | 21 | - |
dc.contributor.affiliatedAuthor | Park, J | - |
dc.identifier.scopusid | 2-s2.0-0012462507 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 18 | - |
dc.description.scptc | 19 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | DYNAMIC KINETIC RESOLUTION | - |
dc.subject.keywordPlus | RUTHENIUM COMPLEXES | - |
dc.subject.keywordPlus | SECONDARY ALCOHOLS | - |
dc.subject.keywordPlus | HYDROGEN-TRANSFER | - |
dc.subject.keywordPlus | CATALYSIS | - |
dc.subject.keywordPlus | HYDRIDE | - |
dc.subject.keywordPlus | ACID | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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