DC Field | Value | Language |
---|---|---|
dc.contributor.author | Rekharsky, MV | - |
dc.contributor.author | Mori, T | - |
dc.contributor.author | Yang, C | - |
dc.contributor.author | Ko, YH | - |
dc.contributor.author | Selvapalam, N | - |
dc.contributor.author | Kim, H | - |
dc.contributor.author | Sobransingh, D | - |
dc.contributor.author | Kaifer, AE | - |
dc.contributor.author | Liu, SM | - |
dc.contributor.author | Isaacs, L | - |
dc.contributor.author | Chen, W | - |
dc.contributor.author | Moghaddam, S | - |
dc.contributor.author | Gilson, MK | - |
dc.contributor.author | Kim, KM | - |
dc.contributor.author | Inoue, Y | - |
dc.date.accessioned | 2015-06-25T03:27:25Z | - |
dc.date.available | 2015-06-25T03:27:25Z | - |
dc.date.created | 2009-02-28 | - |
dc.date.issued | 2007-12-26 | - |
dc.identifier.issn | 0027-8424 | - |
dc.identifier.other | 2015-OAK-0000007393 | en_US |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/12743 | - |
dc.description.abstract | The molecular host cucurbit[7]uril forms an extremely stable inclusion complex with the dicationic ferrocene derivative bis(trimethylammoniomethyl)ferrocene in aqueous solution. The equilibrium association constant for this host-guest pair is 3 x 1015 M-1 (K-d = 3 x 10(-16) M), equivalent to that exhibited by the avidin-biotin pair. Although purely synthetic systems with larger association constants have been reported, the present one is unique because it does not rely on polyvalency. Instead, it achieves its extreme affinity by overcoming the compensatory enthalpy-entropy relationship usually observed in supramolecular complexes. Its disproportionately low entropic cost is traced to extensive host desolvation and to the rigidity of both the host and the guest. | - |
dc.description.statementofresponsibility | open | en_US |
dc.language | English | - |
dc.publisher | NATL ACAD SCIENCES | - |
dc.relation.isPartOf | PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | - |
dc.rights | BY_NC_ND | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/kr | en_US |
dc.title | A synthetic host-guest system achieves avidin-biotin affinity by overcoming enthalpy-entropy compensation | - |
dc.type | Article | - |
dc.contributor.college | 화학과 | en_US |
dc.identifier.doi | 10.1073/pnas.0706407105 | - |
dc.author.google | Rekharsky, MV | en_US |
dc.author.google | Mori, T | en_US |
dc.author.google | Inoue, Y | en_US |
dc.author.google | Kim, KM | en_US |
dc.author.google | Gilson, MK | en_US |
dc.author.google | Moghaddam, S | en_US |
dc.author.google | Chen, W | en_US |
dc.author.google | Isaacs, L | en_US |
dc.author.google | Liu, SM | en_US |
dc.author.google | Kaifer, AE | en_US |
dc.author.google | Sobransingh, D | en_US |
dc.author.google | Kim, H | en_US |
dc.author.google | Selvapalam, N | en_US |
dc.author.google | Ko, YH | en_US |
dc.author.google | Yang, C | en_US |
dc.relation.volume | 104 | en_US |
dc.relation.issue | 52 | en_US |
dc.relation.startpage | 20737 | en_US |
dc.relation.lastpage | 20742 | en_US |
dc.contributor.id | 10104366 | en_US |
dc.relation.journal | PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | en_US |
dc.relation.index | SCI급, SCOPUS 등재논문 | en_US |
dc.relation.sci | SCI | en_US |
dc.collections.name | Journal Papers | en_US |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, v.104, no.52, pp.20737 - 20742 | - |
dc.identifier.wosid | 000252077400023 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 20742 | - |
dc.citation.number | 52 | - |
dc.citation.startPage | 20737 | - |
dc.citation.title | PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA | - |
dc.citation.volume | 104 | - |
dc.contributor.affiliatedAuthor | Kim, KM | - |
dc.identifier.scopusid | 2-s2.0-38049144318 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 346 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | MOLECULAR RECOGNITION | - |
dc.subject.keywordPlus | CUCURBITURIL HOMOLOGS | - |
dc.subject.keywordPlus | BINDING AFFINITIES | - |
dc.subject.keywordPlus | THERMODYNAMICS | - |
dc.subject.keywordPlus | CYCLODEXTRIN | - |
dc.subject.keywordPlus | ENERGY | - |
dc.subject.keywordPlus | LIGAND | - |
dc.subject.keywordPlus | COMPLEXATION | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | CHEMISTRY | - |
dc.subject.keywordAuthor | cucurbituril entropy control | - |
dc.subject.keywordAuthor | ferrocene derivatives | - |
dc.subject.keywordAuthor | host-guest complexation | - |
dc.subject.keywordAuthor | thermodynamics | - |
dc.relation.journalWebOfScienceCategory | Multidisciplinary Sciences | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
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