DC Field | Value | Language |
---|---|---|
dc.contributor.author | Adiyala, Praveen Reddy | - |
dc.contributor.author | Jang, Seungwook | - |
dc.contributor.author | Vishwakarma, Niraj K. | - |
dc.contributor.author | Hwang, Yoon-Ho | - |
dc.contributor.author | Kim, Dong-Pyo | - |
dc.date.accessioned | 2021-12-03T10:02:43Z | - |
dc.date.available | 2021-12-03T10:02:43Z | - |
dc.date.created | 2020-04-20 | - |
dc.date.issued | 2020-02 | - |
dc.identifier.issn | 1463-9262 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/107929 | - |
dc.description.abstract | Visible-light-driven continuous-flow decarboxylative annulation was achieved and used along with a microreactor containing immobilized ruthenium catalyst to construct valuable fused imidazole derivatives with high yields under an open atmosphere. Notably, this chemistry included the use of l-proline and alpha-azidochalcone as precursors of an alpha-amino radical and 2H-azirine via photo-induced decarboxylation and denitrogenation, respectively, to give the annulated imidazole derivatives as a result of the formation of two new C-N bonds. Moreover the novel, environmentally benign and efficient continuous-flow protocol was further improved by carrying out the reaction in a polydimethylsiloxane (PDMS) microreactor with immobilized Ru3+ under fluorescent or white LED light, enabling excellent yields (70-94%) at a reaction time (2 min) significantly shorter than that (16 h) of the batch protocol. | - |
dc.language | English | - |
dc.publisher | ROYAL SOC CHEMISTRY | - |
dc.relation.isPartOf | GREEN CHEMISTRY | - |
dc.title | Continuous-flow photo-induced decarboxylative annulative access to fused imidazole derivatives via a microreactor containing immobilized ruthenium | - |
dc.type | Article | - |
dc.identifier.doi | 10.1039/c9gc03496j | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | GREEN CHEMISTRY, v.22, no.5, pp.1565 - 1571 | - |
dc.identifier.wosid | 000519903900006 | - |
dc.citation.endPage | 1571 | - |
dc.citation.number | 5 | - |
dc.citation.startPage | 1565 | - |
dc.citation.title | GREEN CHEMISTRY | - |
dc.citation.volume | 22 | - |
dc.contributor.affiliatedAuthor | Hwang, Yoon-Ho | - |
dc.contributor.affiliatedAuthor | Kim, Dong-Pyo | - |
dc.identifier.scopusid | 2-s2.0-85082085532 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | 1,2,4,5-TETRASUBSTITUTED IMIDAZOLES | - |
dc.subject.keywordPlus | MULTISUBSTITUTED IMIDAZOLES | - |
dc.subject.keywordPlus | IONIC LIQUIDS | - |
dc.subject.keywordPlus | ALPHA-AMINO-ACIDS | - |
dc.subject.keywordPlus | LIGHT PHOTOREDOX CATALYSIS | - |
dc.subject.keywordPlus | ONE-POT SYNTHESIS | - |
dc.subject.keywordPlus | VINYL AZIDES | - |
dc.subject.keywordPlus | TETRASUBSTITUTED IMIDAZOLES | - |
dc.subject.keywordPlus | MULTICOMPONENT SYNTHESIS | - |
dc.subject.keywordPlus | CARBOXYLIC-ACIDS | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Green & Sustainable Science & Technology | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Science & Technology - Other Topics | - |
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