DC Field | Value | Language |
---|---|---|
dc.contributor.author | Shin, J | - |
dc.contributor.author | Kim, SH | - |
dc.contributor.author | Camblor, MA | - |
dc.contributor.author | Warrender, SJ | - |
dc.contributor.author | Miller, SR | - |
dc.contributor.author | Zhou, WZ | - |
dc.contributor.author | Wright, PA | - |
dc.contributor.author | Hong, SB | - |
dc.date.accessioned | 2015-06-25T01:48:52Z | - |
dc.date.available | 2015-06-25T01:48:52Z | - |
dc.date.created | 2010-05-03 | - |
dc.date.issued | 2010-01 | - |
dc.identifier.issn | 1477-9226 | - |
dc.identifier.other | 2015-OAK-0000021033 | en_US |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/10083 | - |
dc.description.abstract | The synthetic details of a novel potassium gallosilicate natrolite with Si/Ga = 1.28, denoted PST-1, are described. The presence of K+ and Ga with well-defined levels of concentration in the synthesis mixture is essential for directing its crystallisation. PST-1 transforms rapidly into TNU-6 under hydrothermal conditions, behaviour that contrasts sharply with its very high thermal and hydrothermal stability, which is unusual for a material of such a high Ga content. These stability issues are discussed and rationalized based on chemical composition, likely violations of Loewenstein's rule and the temperature of dehydration of as-made K-PST-1. The crystal structure of TNU-6 has been resolved through the combined use of synchrotron X-ray and electron diffraction data; it has the BaFeGaO4 structure type with an additional root 3a x root 3a "GeAlO4" superstructure that arises from tilting of some of the tetrahedral units in all of the 6-rings. | - |
dc.description.statementofresponsibility | open | en_US |
dc.language | English | - |
dc.publisher | Royal Society of Chemistry | - |
dc.relation.isPartOf | DALTON TRANSACTIONS | - |
dc.rights | BY_NC_ND | en_US |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/2.0/kr | en_US |
dc.title | Synthesis and in situ transformation of PST-1: a potassium gallosilicate natrolite with a high Ga content | - |
dc.type | Article | - |
dc.contributor.college | 환경공학부 | en_US |
dc.identifier.doi | 10.1039/b920540n | - |
dc.author.google | Shin, J | en_US |
dc.author.google | Kim, SH | en_US |
dc.author.google | Hong, SB | en_US |
dc.author.google | Wright, PA | en_US |
dc.author.google | Zhou, WZ | en_US |
dc.author.google | Miller, SR | en_US |
dc.author.google | Warrender, SJ | en_US |
dc.author.google | Camblor, MA | en_US |
dc.relation.volume | 39 | en_US |
dc.relation.issue | 9 | en_US |
dc.relation.startpage | 2246 | en_US |
dc.relation.lastpage | 2253 | en_US |
dc.contributor.id | 10077624 | en_US |
dc.relation.journal | DALTON TRANSACTIONS | en_US |
dc.relation.index | SCI급, SCOPUS 등재논문 | en_US |
dc.relation.sci | SCI | en_US |
dc.collections.name | Journal Papers | en_US |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | DALTON TRANSACTIONS, v.39, no.9, pp.2246 - 2253 | - |
dc.identifier.wosid | 000274580800012 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 2253 | - |
dc.citation.number | 9 | - |
dc.citation.startPage | 2246 | - |
dc.citation.title | DALTON TRANSACTIONS | - |
dc.citation.volume | 39 | - |
dc.contributor.affiliatedAuthor | Hong, SB | - |
dc.identifier.scopusid | 2-s2.0-77149144468 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 4 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | CRYSTAL-STRUCTURE | - |
dc.subject.keywordPlus | ZEOLITE | - |
dc.subject.keywordPlus | FRAMEWORK | - |
dc.subject.keywordPlus | GALLIUM | - |
dc.subject.keywordPlus | REFINEMENT | - |
dc.subject.keywordPlus | DISORDER | - |
dc.subject.keywordPlus | NUCLEAR | - |
dc.subject.keywordPlus | TNU-7 | - |
dc.subject.keywordPlus | NAT | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Inorganic & Nuclear | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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