DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kang, Soyeong | - |
dc.contributor.author | Jang, Seok Hyeon | - |
dc.contributor.author | Lee, Juyeol | - |
dc.contributor.author | Kim, Dong-gil | - |
dc.contributor.author | Kim, Mijin | - |
dc.contributor.author | Jeong, Wook | - |
dc.contributor.author | Rhee, Young Ho | - |
dc.date.accessioned | 2018-06-15T05:34:05Z | - |
dc.date.available | 2018-06-15T05:34:05Z | - |
dc.date.created | 2017-10-10 | - |
dc.date.issued | 2017-09 | - |
dc.identifier.issn | 1523-7060 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/50609 | - |
dc.description.abstract | Catalytic asymmetric synthesis of N-heterocyclic glycosides free of protecting and directing groups is reported. The key reaction is highlighted by the atom-efficient and regioselective addition of unprotected pyrimidines to highly functionalized alkoxyallene. Numerous acyclic and cyclic N-heterocyclic glycosides are accessed with minimal formation of organic byproducts. The synthetic utility of the reaction is demonstrated by the first catalytic asymmetric synthesis of anticancer pharmaceutical (-)-Tegafur and stereoselective synthesis of an oxepane nucleoside derivative. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.relation.isPartOf | ORGANIC LETTERS | - |
dc.subject | 5-SUBSTITUTED URACILS | - |
dc.subject | NUCLEOSIDE ANALOGS | - |
dc.subject | ALLYLIC AMINATION | - |
dc.subject | TERMINAL ALLENES | - |
dc.subject | METATHESIS | - |
dc.subject | GLYCOSYLATION | - |
dc.subject | RING | - |
dc.subject | HETEROCYCLES | - |
dc.subject | STRATEGY | - |
dc.subject | AMINES | - |
dc.title | Pd-Catalyzed Regioselective Asymmetric Addition Reaction of Unprotected Pyrimidines to Alkoxyallene | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/acs.orglett.7b02332 | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ORGANIC LETTERS, v.19, no.17, pp.4684 - 4687 | - |
dc.identifier.wosid | 000409566400069 | - |
dc.date.tcdate | 2019-02-01 | - |
dc.citation.endPage | 4687 | - |
dc.citation.number | 17 | - |
dc.citation.startPage | 4684 | - |
dc.citation.title | ORGANIC LETTERS | - |
dc.citation.volume | 19 | - |
dc.contributor.affiliatedAuthor | Kang, Soyeong | - |
dc.contributor.affiliatedAuthor | Jang, Seok Hyeon | - |
dc.contributor.affiliatedAuthor | Lee, Juyeol | - |
dc.contributor.affiliatedAuthor | Kim, Mijin | - |
dc.contributor.affiliatedAuthor | Rhee, Young Ho | - |
dc.identifier.scopusid | 2-s2.0-85028755886 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 10 | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | 5-SUBSTITUTED URACILS | - |
dc.subject.keywordPlus | NUCLEOSIDE ANALOGS | - |
dc.subject.keywordPlus | ALLYLIC AMINATION | - |
dc.subject.keywordPlus | TERMINAL ALLENES | - |
dc.subject.keywordPlus | METATHESIS | - |
dc.subject.keywordPlus | GLYCOSYLATION | - |
dc.subject.keywordPlus | RING | - |
dc.subject.keywordPlus | HETEROCYCLES | - |
dc.subject.keywordPlus | STRATEGY | - |
dc.subject.keywordPlus | AMINES | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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