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FORMATION OF 1,1,12,12-TETRAMETHYL[1.1]SILAFERROCENOPHANE AND POLY(FERROCENYLSILANE) IN THE REACTION OF FERROUS CHLORIDE WITH THE DILITHIUM SALT OF DICYCLOPENTADIENYLDIMETHYLSILANES SCIE SCOPUS
- Title
- FORMATION OF 1,1,12,12-TETRAMETHYL[1.1]SILAFERROCENOPHANE AND POLY(FERROCENYLSILANE) IN THE REACTION OF FERROUS CHLORIDE WITH THE DILITHIUM SALT OF DICYCLOPENTADIENYLDIMETHYLSILANES
- Date Issued
- 1995-03-08
- Publisher
- ELSEVIER SCIENCE SA LAUSANNE
- Abstract
- 1,1,12,12-Tetramethyl[1.1]silaferrocenophane (1) and poly(ferrocenylsilane) (2) were formed as the major products in the reaction of FeCl2 with the dilithium salt of (C5H5)(2)SiMe(2), and the X-ray crystallography for 1 revealed its molecular structure of an anti conformation.
- Keywords
- FERROCENE; SILICON; X-RAY DIFFRACTION; POLYSILANE; CYCLOPENTADIENYL; POLYMER; HIGH-MOLECULAR-WEIGHT; POLYMERIZATION; COMPLEXES; BEHAVIOR; CRYSTAL
- ISSN
- 0022-328X
- Article Type
- Article
- Citation
- JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 489, no. 1-2, page. 23 - 25, 1995-03-08
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Related Researcher
- 김기문KIM, KIMOON
- Dept of Chemistry