Synthesis and characterization of star-shaped aliphatic polyester
SCIE
SCOPUS
- Title
- Synthesis and characterization of star-shaped aliphatic polyester
- Authors
- Shin, YC; Choi, KY; Jin, MY; Hong, SK; Cho, D; Chang, T; Ree, M
- Date Issued
- 2001-04
- Publisher
- POLYMER SOC KOREA
- Abstract
- Several star-polymers with aliphatic cores were synthesized by ring opening polymerization (ROP) of epsilon -caprolactone using stannous 2-ethyl-hexanoate as a catalyst. The star-polymers were thoroughly analyzed by MALDI-TOF mass spectrometry, temperature gradient interaction chromatography and C-13-NMR to obtain detailed information of the molecular structure. The imperfection of the star-polymers seemed to be originated from restricted participation of sterically hindered hydroxyl groups of initiator. The synthesized star-polymers had narrow molecular weight distributions. Various reaction conditions to control the imperfection were studied.
- Keywords
- GRADIENT INTERACTION CHROMATOGRAPHY; FLIGHT MASS-SPECTROMETRY; POLYMERS; NANOPOROSITY; POLYSTYRENE; TIME
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/19553
- ISSN
- 1225-5947
- Article Type
- Article
- Citation
- KOREA POLYMER JOURNAL, vol. 9, no. 2, page. 100 - 106, 2001-04
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