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Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids SCIE SCOPUS

Title
Silver-Mediated Trifluoromethoxylation of Aryl Stannanes and Arylboronic Acids
Authors
Huang, CHLiang, THarada, SLee, ERitter, T
Date Issued
2011-08-31
Publisher
American Chemical Society
Abstract
A silver-mediated cross-coupling of trifluoromethoxide with aryl stannanes and arylboronic acids to give aryl trifluoromethyl ethers is reported. This is the first report of a transition-metal-mediated C-aryl-OCF3 bond formation.
Keywords
ALPHA-FLUORINATED ETHERS; BETA-FLUORIDE ELIMINATION; REDUCTIVE ELIMINATION; BOND-FORMATION; CATALYZED TRIFLUOROMETHYLATION; MEDICINAL CHEMISTRY; BORONIC ACIDS; REACTIVITY; COMPLEXES; PALLADIUM(IV)
URI
https://oasis.postech.ac.kr/handle/2014.oak/15188
DOI
10.1021/JA204861A
ISSN
0002-7863
Article Type
Article
Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 133, no. 34, page. 13308 - 13310, 2011-08-31
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이은성LEE, EUNSUNG
Dept of Chemistry
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