DC Field | Value | Language |
---|---|---|
dc.contributor.author | Yoonjung Jang | - |
dc.contributor.author | Ramalingam Natarajan | - |
dc.contributor.author | Young Ho Ko | - |
dc.contributor.author | Kim, K | - |
dc.date.accessioned | 2016-03-31T08:13:58Z | - |
dc.date.available | 2016-03-31T08:13:58Z | - |
dc.date.created | 2014-03-05 | - |
dc.date.issued | 2014-01-20 | - |
dc.identifier.issn | 1433-7851 | - |
dc.identifier.other | 2014-OAK-0000029165 | - |
dc.identifier.uri | https://oasis.postech.ac.kr/handle/2014.oak/14850 | - |
dc.description.abstract | Cucurbit[7]uril (CB[7]), an uncharged and water-soluble macrocyclic host, binds protonated amino saccharides (D-glucosamine, D-galactosamine, D-mannosamine and 6-amino-6-deoxy-D-glucose) with excellent affinity (K-a=10(3) to 10(4)M(-1)). The host-guest complexation was confirmed by NMR spectroscopy, isothermal titration calorimetry (ITC), and MALDI-TOF mass spectral analyses. NMR analyses revealed that the amino saccharides, except D-mannosamine, are bound as -anomers within the CB[7] cavity. ITC analyses reveal that CB[7] has excellent affinity for binding amino saccharides in water. The maximum affinity was observed for D-galactosamine hydrochloride (K-a=1.6x10(4)M(-1)). Such a strong affinity for any saccharide in water using a synthetic receptor is unprecedented, as is the supramolecular stabilization of an -anomer by the host. | - |
dc.description.statementofresponsibility | X | - |
dc.language | English | - |
dc.publisher | WILEY-V C H VERLAG GMBH | - |
dc.relation.isPartOf | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.subject | calorimetry | - |
dc.subject | host-guest systems | - |
dc.subject | hydrophobic effect | - |
dc.subject | molecular recognition | - |
dc.subject | NMR spectroscopy | - |
dc.subject | SYNTHETIC LECTIN | - |
dc.subject | MOLECULAR RECOGNITION | - |
dc.subject | SUGARS | - |
dc.subject | RECEPTORS | - |
dc.subject | BINDING | - |
dc.subject | AMINOGLYCOSIDES | - |
dc.subject | DERIVATIVES | - |
dc.subject | CHEMISTRY | - |
dc.title | Cucurbit[7]uril: A High-Affinity Host for Encapsulation of Amino Saccharides and Supramolecular Stabilization of Their -Anomers in Water | - |
dc.type | Article | - |
dc.contributor.college | 첨단재료과학부 | - |
dc.identifier.doi | 10.1002/ANIE.201308879 | - |
dc.author.google | Jang, Y | - |
dc.author.google | Natarajan, R | - |
dc.author.google | Ko, YH | - |
dc.author.google | Kim, K | - |
dc.relation.volume | 53 | - |
dc.relation.issue | 4 | - |
dc.relation.startpage | 1003 | - |
dc.relation.lastpage | 1007 | - |
dc.contributor.id | 10104366 | - |
dc.relation.journal | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.relation.index | SCI급, SCOPUS 등재논문 | - |
dc.relation.sci | SCI | - |
dc.collections.name | Journal Papers | - |
dc.type.rims | ART | - |
dc.identifier.bibliographicCitation | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.53, no.4, pp.1003 - 1007 | - |
dc.identifier.wosid | 000329879500014 | - |
dc.date.tcdate | 2019-01-01 | - |
dc.citation.endPage | 1007 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 1003 | - |
dc.citation.title | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | - |
dc.citation.volume | 53 | - |
dc.contributor.affiliatedAuthor | Kim, K | - |
dc.identifier.scopusid | 2-s2.0-84893279821 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.wostc | 38 | - |
dc.description.scptc | 32 | * |
dc.date.scptcdate | 2018-05-121 | * |
dc.type.docType | Article | - |
dc.subject.keywordPlus | SYNTHETIC LECTIN | - |
dc.subject.keywordPlus | MOLECULAR RECOGNITION | - |
dc.subject.keywordPlus | SUGARS | - |
dc.subject.keywordPlus | DERIVATIVES | - |
dc.subject.keywordPlus | RECEPTORS | - |
dc.subject.keywordPlus | BINDING | - |
dc.subject.keywordAuthor | calorimetry | - |
dc.subject.keywordAuthor | host-guest systems | - |
dc.subject.keywordAuthor | hydrophobic effect | - |
dc.subject.keywordAuthor | molecular recognition | - |
dc.subject.keywordAuthor | NMR spectroscopy | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalResearchArea | Chemistry | - |
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