Development of a high-performance anode for lithium ion batteries using novel ordered mesoporous tungsten oxide materials with high electrical conductivity
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SCOPUS
- Title
- Development of a high-performance anode for lithium ion batteries using novel ordered mesoporous tungsten oxide materials with high electrical conductivity
- Authors
- Yoon, S; Jo, C; Noh, SY; Lee, CW; Song, JH; Lee, J
- Date Issued
- 2011-01
- Publisher
- ROYAL SOC CHEMISTRY
- Abstract
- An ordered mesoporous WO3-X with high electrical conductivity (m-WO3-X) was prepared and evaluated as an anode material for lithium ion batteries (LIBs). Ordered mesoporous tungsten trioxide (m-WO3) with an identical pore structure to that of m-WO3-X and bulk WO3-X (b-WO3-X) was prepared for the comparison purpose. An m-WO3-X electrode exhibited a high reversible capacity (748 mAh g(-1), 6.5 Li/W) and a high volumetric capacity (similar to 1500 mAh cm(-3)), which is comparable to the Li metal itself (ca. 2000 mAh cm(-3)). Also, an improved rate capability and a good cyclability were observed in the m-WO3-X electrode when compared with m-WO3 and b-WO3-X electrodes. From electrochemical impedance spectroscopy (EIS) analysis, the advanced anode performance of the m-WO3-X electrode was probably attributed to large ordered mesopores and a high electrical conductivity. Differential scanning calorimetry (DSC) result displayed that the safety of m-WO3-X was more improved than those of graphite and Si anode materials.
- URI
- https://oasis.postech.ac.kr/handle/2014.oak/11903
- DOI
- 10.1039/C1CP20940J
- ISSN
- 1463-9076
- Article Type
- Article
- Citation
- PHYSICAL CHEMISTRY CHEMICAL PHYSICS, vol. 13, no. 23, page. 11060 - 11066, 2011-01
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